{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,2]],"date-time":"2026-10-02T04:01:47Z","timestamp":1790913707617,"version":"4.1.0"},"reference-count":63,"publisher":"Wiley","issue":"21","license":[{"start":{"date-parts":[[2022,3,23]],"date-time":"2022-03-23T00:00:00Z","timestamp":1647993600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100001659","name":"Deutsche Forschungsgemeinschaft","doi-asserted-by":"publisher","award":["EXC 2008 - 390540038 - UniSysCat"],"award-info":[{"award-number":["EXC 2008 - 390540038 - UniSysCat"]}],"id":[{"id":"10.13039\/501100001659","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2022,5,16]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>Covalent organic frameworks (COFs) are structurally tuneable, porous and crystalline polymers constructed through the covalent attachment of small organic building blocks as elementary units. Using the myriad of such building blocks, a broad spectrum of functionalities has been applied for COF syntheses for broad applications, including heterogeneous catalysis. Herein, we report the synthesis of a new family of porous and crystalline COFs using a novel acridine linker and benzene\u20101,3,5\u2010tricarbaldehyde derivatives bearing a variable number of hydroxy groups. With the broad absorption in the visible light region, the COFs were applied as photocatalysts in metallaphotocatalytic C\u2212N cross\u2010coupling. The fully \u03b2\u2010ketoenamine linked COF showed the highest activity, due to the increased charge separation upon irradiation. The COF showed good to excellent yields for several aryl bromides, good recyclability and even catalyzed the organic transformation in presence of green light as energy source.<\/jats:p>","DOI":"10.1002\/anie.202117738","type":"journal-article","created":{"date-parts":[[2022,2,21]],"date-time":"2022-02-21T10:46:13Z","timestamp":1645440373000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":195,"title":["Acridine\u2010Functionalized Covalent Organic Frameworks (COFs) as Photocatalysts for Metallaphotocatalytic C\u2212N Cross\u2010Coupling"],"prefix":"10.1002","volume":"61","author":[{"given":"Michael","family":"Traxler","sequence":"first","affiliation":[{"name":"Department of Chemistry\/Functional Materials Technische Universit\u00e4t Berlin  Hardenbergstra\u00dfe 40 10623 Berlin Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sebastian","family":"Gisbertz","sequence":"additional","affiliation":[{"name":"Department of Biomolecular Systems Max Planck Institute of Colloids and Interfaces  Am M\u00fchlenberg 1 14476 Potsdam Germany"},{"name":"Department of Chemistry and Biochemistry Freie Universit\u00e4t Berlin  Takustra\u00dfe 3 14195 Berlin Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Pradip","family":"Pachfule","sequence":"additional","affiliation":[{"name":"Department of Chemistry\/Functional Materials Technische Universit\u00e4t Berlin  Hardenbergstra\u00dfe 40 10623 Berlin Germany"},{"name":"Department of Chemical, Biological &amp; Macro-Molecular Sciences S. N. Bose National Centre for Basic Sciences  Kolkata 700106 India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Johannes","family":"Schmidt","sequence":"additional","affiliation":[{"name":"Department of Chemistry\/Functional Materials Technische Universit\u00e4t Berlin  Hardenbergstra\u00dfe 40 10623 Berlin Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"J\u00e9r\u00f4me","family":"Roeser","sequence":"additional","affiliation":[{"name":"Department of Chemistry\/Functional Materials Technische Universit\u00e4t Berlin  Hardenbergstra\u00dfe 40 10623 Berlin Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Susanne","family":"Reischauer","sequence":"additional","affiliation":[{"name":"Department of Biomolecular Systems Max Planck Institute of Colloids and Interfaces  Am M\u00fchlenberg 1 14476 Potsdam Germany"},{"name":"Department of Chemistry and Biochemistry Freie Universit\u00e4t Berlin  Takustra\u00dfe 3 14195 Berlin Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jabor","family":"Rabeah","sequence":"additional","affiliation":[{"name":"Leibniz Institute for Catalysis (LIKAT Rostock) Universit\u00e4t Rostock  18059 Rostock Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Bartholom\u00e4us","family":"Pieber","sequence":"additional","affiliation":[{"name":"Department of Biomolecular Systems Max Planck Institute of Colloids and Interfaces  Am M\u00fchlenberg 1 14476 Potsdam Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2130-4930","authenticated-orcid":false,"given":"Arne","family":"Thomas","sequence":"additional","affiliation":[{"name":"Department of Chemistry\/Functional Materials Technische Universit\u00e4t Berlin  Hardenbergstra\u00dfe 40 10623 Berlin Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2022,3,23]]},"reference":[{"key":"e_1_2_7_1_1","doi-asserted-by":"publisher","DOI":"10.1039\/c2cs35157a"},{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.1628"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.aal1585"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.8b10334"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.9b00550"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9CS00879A"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1039\/C2CS35072F"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.5b00369"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6b08815"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41570-017-0056"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.8b01774"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201905886"},{"key":"e_1_2_7_12_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201905886"},{"key":"e_1_2_7_13_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0CS01027H"},{"key":"e_1_2_7_14_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja803247y"},{"key":"e_1_2_7_15_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9CS00827F"},{"key":"e_1_2_7_16_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.201700387"},{"key":"e_1_2_7_17_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscentsci.0c00463"},{"key":"e_1_2_7_18_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.enchem.2020.100048"},{"key":"e_1_2_7_19_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0CS01569E"},{"key":"e_1_2_7_20_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.201705553"},{"key":"e_1_2_7_21_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1EE01310F"},{"key":"e_1_2_7_22_1","doi-asserted-by":"publisher","DOI":"10.1038\/natrevmats.2016.68"},{"key":"e_1_2_7_23_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja308278w"},{"key":"e_1_2_7_24_1","doi-asserted-by":"publisher","DOI":"10.1002\/cptc.202000014"},{"key":"e_1_2_7_25_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.8b00571"},{"key":"e_1_2_7_26_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.macromol.1c00574"},{"key":"e_1_2_7_27_1","doi-asserted-by":"publisher","DOI":"10.1039\/C7TA07691F"},{"key":"e_1_2_7_28_1","doi-asserted-by":"publisher","DOI":"10.1002\/cssc.201601702"},{"key":"e_1_2_7_29_1","doi-asserted-by":"publisher","DOI":"10.1002\/cptc.201900263"},{"key":"e_1_2_7_30_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9GC00022D"},{"key":"e_1_2_7_31_1","doi-asserted-by":"publisher","DOI":"10.1002\/ange.202101036"},{"key":"e_1_2_7_32_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1GC01902C"},{"key":"e_1_2_7_33_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jmedchem.5b01409"},{"key":"e_1_2_7_34_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41929-020-0473-6"},{"key":"e_1_2_7_35_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.0c03950"},{"key":"e_1_2_7_36_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9SC02601K"},{"key":"e_1_2_7_37_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.aac8343"},{"key":"e_1_2_7_38_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b06599"},{"key":"e_1_2_7_39_1","doi-asserted-by":"publisher","DOI":"10.1016\/1010-6030(91)87070-C"},{"key":"e_1_2_7_40_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja505755k"},{"key":"e_1_2_7_41_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-020-18583-6"},{"key":"e_1_2_7_42_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.9b02951"},{"key":"e_1_2_7_43_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201916710"},{"key":"e_1_2_7_43_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201916710"},{"key":"e_1_2_7_44_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.0c03440"},{"key":"e_1_2_7_45_1","doi-asserted-by":"publisher","DOI":"10.1002\/cber.19310640862"},{"key":"e_1_2_7_46_1","doi-asserted-by":"publisher","DOI":"10.1039\/c3nj00285c"},{"key":"e_1_2_7_47_1","doi-asserted-by":"publisher","DOI":"10.1039\/jr9480001225"},{"key":"e_1_2_7_48_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c00054"},{"key":"e_1_2_7_49_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.1c06518"},{"key":"e_1_2_7_50_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202013852"},{"key":"e_1_2_7_50_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.202013852"},{"key":"e_1_2_7_51_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201607812"},{"key":"e_1_2_7_51_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201607812"},{"key":"e_1_2_7_52_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.8b08088"},{"key":"e_1_2_7_53_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201106656"},{"key":"e_1_2_7_53_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201106656"},{"key":"e_1_2_7_54_1","doi-asserted-by":"publisher","DOI":"10.1021\/cm500034p"},{"key":"e_1_2_7_55_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.8b03744"},{"key":"e_1_2_7_56_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.aag0209"},{"key":"e_1_2_7_57_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.aaw3254"},{"key":"e_1_2_7_58_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9CC00987F"}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.202117738","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/anie.202117738","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.202117738","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,15]],"date-time":"2025-10-15T13:07:12Z","timestamp":1760533632000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.202117738"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2022,3,23]]},"references-count":63,"journal-issue":{"issue":"21","published-print":{"date-parts":[[2022,5,16]]}},"alternative-id":["10.1002\/anie.202117738"],"URL":"https:\/\/doi.org\/10.1002\/anie.202117738","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2022,3,23]]},"assertion":[{"value":"2021-12-28","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2022-03-23","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e202117738"}}