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Here, we design a DRM photocatalyst Rh\/Ce\n                    <jats:sub>\n                      <jats:italic>x<\/jats:italic>\n                    <\/jats:sub>\n                    WO\n                    <jats:sub>3<\/jats:sub>\n                    that invokes both photothermal and photoelectric processes, which overcomes the thermodynamic limitation of DRM under conventional conditions. In contrast to plasmonic or UV\u2010response photocatalysts, our photocatalyst produces a superior light\u2010to\u2010chemical energy efficiency (LTCEE) of 4.65\u2009% with a moderate light intensity. We propose that a light\u2010induced metal\u2010to\u2010metal charge transfer plays a crucial role in the DRM reaction, which induces a redox looping between Ce to W species to lower the activation energy. Quantum mechanical studies reveal that a high oxygen mobility of Ce\n                    <jats:sub>\n                      <jats:italic>x<\/jats:italic>\n                    <\/jats:sub>\n                    WO\n                    <jats:sub>3<\/jats:sub>\n                    , accompanied with the formation of oxo\u2010bridge species, results in a substantial elimination of deposited C species during the reaction. Our catalyst design strategy could offer a promising energy\u2010efficient industrial process for DRM.\n                  <\/jats:p>","DOI":"10.1002\/anie.202200567","type":"journal-article","created":{"date-parts":[[2022,3,11]],"date-time":"2022-03-11T23:48:46Z","timestamp":1647042526000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":139,"title":["Light\u2010Induced Redox Looping of a Rhodium\/Ce\n                    <sub>\n                      <i>x<\/i>\n                    <\/sub>\n                    WO\n                    <sub>3<\/sub>\n                    Photocatalyst for Highly Active and Robust Dry Reforming of Methane"],"prefix":"10.1002","volume":"61","author":[{"given":"Yuying","family":"Yang","sequence":"first","affiliation":[{"name":"Beijng National Laboratory for Molecular Sciences State Key laboratory for Structural Chemistry of Unstable Species College of Chemistry and Molecular Engineering Peking 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