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The physicochemical properties of such membranes mostly depend on their selectively chosen functional building blocks. In this work, we have introduced a novel concept of functional switchability of three\u2010dimensional covalent organic framework (3D\u2010COF) membranes through a simple solvent\u2010influenced fragmentation method. This room\u2010temperature interfacial synthesis provides free\u2010standing 3D\u2010COF membranes with distinct physicochemical properties from the same building monomers. Notably, the change of solvent from chloroform to ethyl acetate switches the membrane property from hydrophilic (water contact angle 60\u00b0) to hydrophobic (water contact angle 142\u00b0) nature. The hydrophobic 3D\u2010COF membrane selectively passes oil molecules from an oil\u2013water emulsion with a gravitational flux of 1536\u2005L\u2009m\n                    <jats:sup>\u22122<\/jats:sup>\n                    \u2009h\n                    <jats:sup>\u22121<\/jats:sup>\n                    .\n                  <\/jats:p>","DOI":"10.1002\/anie.202200905","type":"journal-article","created":{"date-parts":[[2022,1,23]],"date-time":"2022-01-23T21:58:28Z","timestamp":1642975108000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":49,"title":["Solvent\u2010Influenced Fragmentations in Free\u2010Standing Three\u2010Dimensional Covalent Organic Framework Membranes for Hydrophobicity Switching"],"prefix":"10.1002","volume":"61","author":[{"given":"Abdul Khayum","family":"Mohammed","sequence":"first","affiliation":[{"name":"Department of Chemistry Khalifa University Abu Dhabi United Arab 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