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Herein, a pair of chiral Cu<jats:sup>I<\/jats:sup> coordination polymers (<jats:bold>1\u2010M<\/jats:bold> and <jats:bold>1\u2010P<\/jats:bold>) have been prepared by the asymmetrical assembly of achiral ligands and Cu<jats:sub>2<\/jats:sub>I<jats:sub>2<\/jats:sub> clusters. The compounds display dual emission bands and can be used as single\u2010phase white\u2010light phosphors, achieving a \u201cwarm\u201d\u2010white\u2010light\u2010emitting diode with an ultra\u2010high color rendering index (CRI) of 93.4 and an appropriate correlated color temperature (CCT) of 3632\u2005K. Meanwhile, corresponding CPL signals with maximum dissymmetry factor |<jats:italic>g<\/jats:italic><jats:sub>lum<\/jats:sub>|=8\u00d710<jats:sup>\u22123<\/jats:sup> have been observed. Hence, intrinsic white\u2010light emission and CPL have been realized simultaneously in coordination polymers for the first time. This work gains insight into the nature of chiral assembly from achiral units and offers a prospect for the development of single\u2010phase white\u2010CPL materials.<\/jats:p>","DOI":"10.1002\/anie.202201590","type":"journal-article","created":{"date-parts":[[2022,3,15]],"date-time":"2022-03-15T03:16:18Z","timestamp":1647314178000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":75,"title":["White\u2010Light Emission and Circularly Polarized Luminescence from a Chiral Copper(I) Coordination Polymer through Symmetry\u2010Breaking Crystallization"],"prefix":"10.1002","volume":"61","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-8205-5811","authenticated-orcid":false,"given":"Mu\u2010Xin","family":"Yu","sequence":"first","affiliation":[{"name":"State Key Laboratory of Structure Chemistry Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences  Fuzhou Fujian 350002 China"},{"name":"Organic 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