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Stacked porous organic molecular frameworks (POMFs) capable of noncovalent \u03c0\u22c5\u22c5\u22c5\u03c0 interactions are emerging as a new kind of adsorbents that facilitate green separation. Here we report a robust porous molecular crystal (<jats:bold>TAPM\u20101<\/jats:bold>), which is stabilized by multiple intermolecular \u03c0\u22c5\u22c5\u22c5\u03c0 interactions. With its long\u2010range \u03c0\u2010stacking, <jats:bold>TAPM\u20101<\/jats:bold> has excellent hydrophobicity, thermostability, recyclability, and high selectivity for aromatics over the corresponding cyclic aliphatics. This enables <jats:bold>TAPM\u20101<\/jats:bold> to serve as the stationary phase in the high\u2010resolution gas chromatographic separation of benzene and cyclohexane or toluene and methylcyclohexane.<\/jats:p>","DOI":"10.1002\/anie.202201646","type":"journal-article","created":{"date-parts":[[2022,3,30]],"date-time":"2022-03-30T06:33:36Z","timestamp":1648622016000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":44,"title":["A Noncovalent \u03c0\u2010Stacked Porous Organic Molecular Framework for Selective Separation of Aromatics and Cyclic Aliphatics"],"prefix":"10.1002","volume":"61","author":[{"given":"Cheng","family":"Chen","sequence":"first","affiliation":[{"name":"State Key Lab of Structural Chemistry Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences  Fuzhou 350002 China"},{"name":"Fujian Science &amp; Technology Innovation Laboratory for Optoelectronic Information of China  Fuzhou 350108 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Haiyan","family":"Guan","sequence":"additional","affiliation":[{"name":"State Key Lab of Structural Chemistry Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences  Fuzhou 350002 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hengbo","family":"Li","sequence":"additional","affiliation":[{"name":"State Key Lab of Structural Chemistry Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences  Fuzhou 350002 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yunzhe","family":"Zhou","sequence":"additional","affiliation":[{"name":"State Key Lab of Structural Chemistry Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences  Fuzhou 350002 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yougui","family":"Huang","sequence":"additional","affiliation":[{"name":"State Key Lab of Structural Chemistry Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences  Fuzhou 350002 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wei","family":"Wei","sequence":"additional","affiliation":[{"name":"Department of Chemistry Capital Normal University  Beijing 100048 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Maochun","family":"Hong","sequence":"additional","affiliation":[{"name":"State Key Lab of Structural Chemistry Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences  Fuzhou 350002 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2610-285X","authenticated-orcid":false,"given":"Mingyan","family":"Wu","sequence":"additional","affiliation":[{"name":"State Key Lab of Structural Chemistry Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences  Fuzhou 350002 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