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The F\n                    <jats:sub>430<\/jats:sub>\n                    and P450nor co\u2010factors, with their reduced Ni\n                    <jats:sup>I<\/jats:sup>\n                    \u2010 and Fe\n                    <jats:sup>III<\/jats:sup>\n                    \u2010containing tetrapyrrolic cores, are prototypical examples of biological systems involved in methane formation and in the reduction of nitric oxide, respectively. Herein, using a comprehensive range of experimental and theoretical methods, we raise evidence that nickel tetraphenyl porphyrins deposited in vacuo on a copper surface are reactive towards nitric oxide disproportionation at room temperature. The interpretation of the measurements is far from being straightforward due to the high reactivity of the different nitrogen oxides species (eventually present in the residual gas background) and of the possible reaction intermediates. 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