{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,20]],"date-time":"2026-08-20T10:01:36Z","timestamp":1787220096645,"version":"build-2736575974"},"reference-count":38,"publisher":"Wiley","issue":"29","license":[{"start":{"date-parts":[[2022,6,1]],"date-time":"2022-06-01T00:00:00Z","timestamp":1654041600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100001381","name":"National Research Foundation Singapore","doi-asserted-by":"publisher","award":["A-0004543-00-00"],"award-info":[{"award-number":["A-0004543-00-00"]}],"id":[{"id":"10.13039\/501100001381","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100004378","name":"Shell","doi-asserted-by":"publisher","award":["A-0004543-01-00"],"award-info":[{"award-number":["A-0004543-01-00"]}],"id":[{"id":"10.13039\/100004378","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2022,7,18]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Electrocatalytic carbon monoxide reduction has been previously reported to yield a range of carbonaceous products including alcohols, hydrocarbons and carboxylic acids. However, esters, an important family of organic compounds, have not been formed. Herein, we report the electrosynthesis of C\n                    <jats:sub>3<\/jats:sub>\n                    to C\n                    <jats:sub>6<\/jats:sub>\n                    acetate esters (H\n                    <jats:sub>3<\/jats:sub>\n                    C\u2212(C=O)\u2212O\u2212R) from carbon monoxide using copper catalysts in a membrane electrode assembly cell. Ethyl acetate and propyl acetate could be produced with an unprecedented total Faradaic efficiency (\n                    <jats:italic>FE<\/jats:italic>\n                    ) of \u223c22\u2009% and with a current density of up to \u221255\u2005mA\u2009cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    , alongside minor quantities of methyl acetate and butyl acetate. The esters are produced via the addition reaction of ethenone (H\n                    <jats:sub>2<\/jats:sub>\n                    C=C=O) and alcohols produced during CO reduction. We show that the near water\u2010free reaction conditions and the high local pH play key roles in the formation of the esters.\n                  <\/jats:p>","DOI":"10.1002\/anie.202202859","type":"journal-article","created":{"date-parts":[[2022,5,10]],"date-time":"2022-05-10T10:56:41Z","timestamp":1652180201000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":39,"title":["Production of C\n                    <sub>3<\/sub>\n                    \u2013C\n                    <sub>6<\/sub>\n                    Acetate Esters via CO Electroreduction in a Membrane Electrode Assembly Cell"],"prefix":"10.1002","volume":"61","author":[{"given":"Yansong","family":"Zhou","sequence":"first","affiliation":[{"name":"Department of Chemistry Faculty of Science National University of Singapore  3 Science Drive 3 Singapore 117543 Singapore"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ramesha","family":"Ganganahalli","sequence":"additional","affiliation":[{"name":"Shell India Markets Private LTD  Plot No. 7, Bengaluru Hardware Park, Mahadeva, Kodigehalli Bangalore North 562149 India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sumit","family":"Verma","sequence":"additional","affiliation":[{"name":"Shell International Exploration &amp; Production Inc.  3333 Highway 6 South Houston TX 77082 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hui Ru","family":"Tan","sequence":"additional","affiliation":[{"name":"Institute of Materials Research and Engineering (IMRE) Agency of Science Technology, and Research (A*STAR)  2 Fusionopolis Way, #08-03 Innovis 138634 Singapore"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1609-0867","authenticated-orcid":false,"given":"Boon Siang","family":"Yeo","sequence":"additional","affiliation":[{"name":"Department of Chemistry Faculty of Science National University of Singapore  3 Science Drive 3 Singapore 117543 Singapore"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2022,6]]},"reference":[{"key":"e_1_2_7_1_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1CS00535A"},{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-021-23023-0"},{"key":"e_1_2_7_3_1","unstructured":"\u00a0"},{"key":"e_1_2_7_4_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41929-018-0133-2"},{"key":"e_1_2_7_5_2","doi-asserted-by":"publisher","DOI":"10.1038\/nature13249"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1073\/pnas.1821683117"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41929-019-0269-8"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-019-13190-6"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1201\/9780367802493"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1002\/cber.189502803176"},{"key":"e_1_2_7_11_1","unstructured":"\u00a0"},{"key":"e_1_2_7_12_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202008289"},{"key":"e_1_2_7_12_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.202008289"},{"key":"e_1_2_7_13_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41929-022-00757-8"},{"key":"e_1_2_7_14_1","unstructured":"\u00a0"},{"key":"e_1_2_7_15_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202102657"},{"key":"e_1_2_7_15_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.202102657"},{"key":"e_1_2_7_16_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201910155"},{"key":"e_1_2_7_16_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201910155"},{"key":"e_1_2_7_17_1","doi-asserted-by":"publisher","DOI":"10.1039\/c2ee21234j"},{"key":"e_1_2_7_18_1","unstructured":"\u00a0"},{"key":"e_1_2_7_19_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-020-16998-9"},{"key":"e_1_2_7_20_2","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.5b02550"},{"key":"e_1_2_7_21_1","unstructured":"\u00a0"},{"key":"e_1_2_7_22_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41560-020-00761-x"},{"key":"e_1_2_7_23_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.joule.2019.07.021"},{"key":"e_1_2_7_24_1","doi-asserted-by":"publisher","DOI":"10.1038\/nmat4738"},{"key":"e_1_2_7_25_1","unstructured":"\u00a0"},{"key":"e_1_2_7_26_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.aas9100"},{"key":"e_1_2_7_27_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jelechem.2013.08.033"},{"key":"e_1_2_7_28_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5b11390"},{"key":"e_1_2_7_29_1","unstructured":"\u00a0"},{"key":"e_1_2_7_30_2","doi-asserted-by":"publisher","DOI":"10.1021\/jz201461p"},{"key":"e_1_2_7_31_2","first-page":"9735","volume":"142","author":"Zhao Y.","year":"2020","journal-title":"J. Am. Chem. Soc."},{"key":"e_1_2_7_32_2","doi-asserted-by":"publisher","DOI":"10.1039\/c0ee00071j"},{"key":"e_1_2_7_33_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41560-021-00813-w"},{"key":"e_1_2_7_34_1","doi-asserted-by":"publisher","DOI":"10.1126\/sciadv.abd2569"},{"key":"e_1_2_7_35_1","first-page":"280","volume":"10","author":"Fan Q.","year":"2018","journal-title":"Mater. Today"}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.202202859","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/anie.202202859","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.202202859","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,8,21]],"date-time":"2023-08-21T12:22:08Z","timestamp":1692620528000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.202202859"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2022,6]]},"references-count":38,"journal-issue":{"issue":"29","published-print":{"date-parts":[[2022,7,18]]}},"alternative-id":["10.1002\/anie.202202859"],"URL":"https:\/\/doi.org\/10.1002\/anie.202202859","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2022,6]]},"assertion":[{"value":"2022-02-22","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2022-06-01","order":2,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e202202859"}}