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In contrast, little is known about Dewar metallabenzenes having a transition metal in the skeletal framework, despite the recent intensive interest in the development of chemistry of metallabenzenes. Herein, we report the isolation and characterization of the first examples of structurally characterized Dewar metallabenzenes. These compounds were generated via unprecedented reactions of metallacyclobutadienes with aminoalkynes.<\/jats:p>","DOI":"10.1002\/anie.202202886","type":"journal-article","created":{"date-parts":[[2022,4,20]],"date-time":"2022-04-20T08:03:51Z","timestamp":1650441831000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":17,"title":["Dewar Metallabenzenes from Reactions of Metallacyclobutadienes with Alkynes"],"prefix":"10.1002","volume":"61","author":[{"given":"Wei","family":"Wei","sequence":"first","affiliation":[{"name":"Department of Chemistry Hong Kong University of Science and Technology  Clear Water Bay, Kowloon Hong Kong China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xin","family":"Xu","sequence":"additional","affiliation":[{"name":"Department of Chemistry Hong Kong University of Science and Technology  Clear Water Bay, Kowloon Hong Kong China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Herman H. 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