{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,7]],"date-time":"2026-09-07T11:39:12Z","timestamp":1788781152789,"version":"build-2803163510"},"reference-count":30,"publisher":"Wiley","issue":"30","license":[{"start":{"date-parts":[[2022,6,10]],"date-time":"2022-06-10T00:00:00Z","timestamp":1654819200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100008982","name":"National Science Foundation of Sri Lanka","doi-asserted-by":"publisher","award":["1847674"],"award-info":[{"award-number":["1847674"]}],"id":[{"id":"10.13039\/501100008982","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2022,7,25]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Zinc metal represents a low\u2010cost, high\u2010capacity anode material to develop energy\u2010dense aqueous redox\u2010flow batteries (RFB). However, the energy\u2010storage applications of traditional inorganic Zn halide flow batteries are primarily plagued by the material challenges of traditional halide cathode electrolytes (e.g., bromine), including corrosion, toxicity, and severe crossover. Herein, we report a bipolar zinc\u2013ferrocene salt compound, zinc 1,1\u2032\u2010bis(3\u2010sulfonatopropyl)ferrocene,\n                    <jats:bold>\n                      Zn[Fc(SPr)\n                      <jats:sub>2<\/jats:sub>\n                      ]\n                    <\/jats:bold>\n                    (1.80\u2005M solubility or 48.2\u2005Ah\u2009L\n                    <jats:sup>\u2212<\/jats:sup>\n                    charge storage capacity)\u2014a robust, energy\u2010dense, bipolar redox\u2010active electrolyte material for RFBs.\n                    <jats:bold>\n                      Zn[Fc(SPr)\n                      <jats:sub>2<\/jats:sub>\n                      ]\n                    <\/jats:bold>\n                    \u2010based redox\u2010flow batteries operated at high current densities of up to 200\u2005mA\u2009cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    and delivered an energy efficiency of up to 81.5\u2009% and a power density of up to 270.5\u2005mW\u2009cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    . A Zn[Fc(SPr)\n                    <jats:sub>2<\/jats:sub>\n                    ] flow battery demonstrated an energy density of 20.2\u2005Wh\u2009L\n                    <jats:sup>\u22121<\/jats:sup>\n                    and displayed nearly 100\u2009% capacity retention for 2000\u2005cycles (1284\u2005h or 53.5\u2005days).\n                  <\/jats:p>","DOI":"10.1002\/anie.202204030","type":"journal-article","created":{"date-parts":[[2022,5,6]],"date-time":"2022-05-06T22:19:35Z","timestamp":1651875575000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":54,"title":["An Energy\u2010Dense, Powerful, Robust Bipolar Zinc\u2013Ferrocene Redox\u2010Flow Battery"],"prefix":"10.1002","volume":"61","author":[{"given":"Jian","family":"Luo","sequence":"first","affiliation":[{"name":"Department of Chemistry and Biochemistry Utah State University  0300 Old Main Hill Logan UT 84322 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Bo","family":"Hu","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Biochemistry Utah State University  0300 Old Main Hill Logan UT 84322 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Maowei","family":"Hu","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Biochemistry Utah State University  0300 Old Main Hill Logan UT 84322 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wenda","family":"Wu","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Biochemistry Utah State University  0300 Old Main Hill Logan UT 84322 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3698-1096","authenticated-orcid":false,"given":"T. Leo","family":"Liu","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Biochemistry Utah State University  0300 Old Main Hill Logan UT 84322 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2022,6,10]]},"reference":[{"key":"e_1_2_7_1_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201505000"},{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsenergylett.6b00655"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6b10984"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chempr.2017.11.001"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.joule.2018.07.005"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.1212741"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsenergylett.9b01332"},{"key":"e_1_2_7_8_1","first-page":"1","volume-title":"Encyclopedia of Inorganic and Bioinorganic Chemistry","author":"Hu B.","year":"2019"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jpowsour.2017.05.057"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsenergylett.7b00650"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1039\/C7CS00569E"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.201501449"},{"key":"e_1_2_7_13_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201606472"},{"key":"e_1_2_7_13_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201606472"},{"key":"e_1_2_7_14_1","doi-asserted-by":"crossref","unstructured":"T.Liu B.Hu C.Debruler J.Luo U.S. Patent 10 934 258 2021.","DOI":"10.3390\/mi11100934"},{"key":"e_1_2_7_15_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41560-018-0167-3"},{"key":"e_1_2_7_16_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201907934"},{"key":"e_1_2_7_16_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201907934"},{"key":"e_1_2_7_17_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.joule.2018.10.010"},{"key":"e_1_2_7_18_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.201900039"},{"key":"e_1_2_7_19_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201901052"},{"key":"e_1_2_7_20_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.joule.2019.06.007"},{"key":"e_1_2_7_21_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.joule.2019.08.025"},{"key":"e_1_2_7_22_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsenergylett.7b00019"},{"key":"e_1_2_7_23_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ensm.2020.04.020"},{"key":"e_1_2_7_24_1","doi-asserted-by":"publisher","DOI":"10.1149\/1945-7111\/ab84f8"},{"key":"e_1_2_7_25_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.nanoen.2017.10.057"},{"key":"e_1_2_7_26_1","doi-asserted-by":"publisher","DOI":"10.1149\/2.0891807jes"},{"key":"e_1_2_7_27_1","doi-asserted-by":"publisher","DOI":"10.1149\/2.0151601jes"},{"key":"e_1_2_7_28_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.electacta.2011.04.111"}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.202204030","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/anie.202204030","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.202204030","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,8,24]],"date-time":"2023-08-24T02:22:48Z","timestamp":1692843768000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.202204030"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2022,6,10]]},"references-count":30,"journal-issue":{"issue":"30","published-print":{"date-parts":[[2022,7,25]]}},"alternative-id":["10.1002\/anie.202204030"],"URL":"https:\/\/doi.org\/10.1002\/anie.202204030","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2022,6,10]]},"assertion":[{"value":"2022-03-17","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2022-06-10","order":2,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e202204030"}}