{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,17]],"date-time":"2026-08-17T14:29:59Z","timestamp":1786976999325,"version":"build-2736575974"},"reference-count":81,"publisher":"Wiley","issue":"25","license":[{"start":{"date-parts":[[2022,4,25]],"date-time":"2022-04-25T00:00:00Z","timestamp":1650844800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100000038","name":"Natural Sciences and Engineering Research Council of Canada","doi-asserted-by":"publisher","award":["RGPIN201805574"],"award-info":[{"award-number":["RGPIN201805574"]}],"id":[{"id":"10.13039\/501100000038","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100006770","name":"American Chemical Society Petroleum Research Fund","doi-asserted-by":"publisher","award":["61870-ND3"],"award-info":[{"award-number":["61870-ND3"]}],"id":[{"id":"10.13039\/100006770","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2022,6,20]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Tetraarylmethanes and adamantanes are important rigid covalent connectors that play a four\u2010way scaffolding role in molecular and materials chemistry. We report the synthesis of a new tetravalent phosphaza\u2010adamantane cage, (PNSiMe\n                    <jats:sub>3<\/jats:sub>\n                    )\n                    <jats:sub>4<\/jats:sub>\n                    (NMe)\n                    <jats:sub>6<\/jats:sub>\n                    (\n                    <jats:bold>2<\/jats:bold>\n                    ), that shows high thermal, air, and redox stability due to its geometry. It nevertheless participates in covalent four\u2010fold functionalization reactions along its periphery. The combination of a robust core and reactive corona makes\n                    <jats:bold>2<\/jats:bold>\n                    a convenient inorganic scaffold upon which tetrahedral molecular and macromolecular chemistry can be constructed. This potential is demonstrated by the synthesis of a tetrakis(bis(phosphine)iminium) ion (in compound\n                    <jats:bold>3<\/jats:bold>\n                    ) and the first all P\/N poly(phosphazene) network (\n                    <jats:bold>5<\/jats:bold>\n                    ).\n                  <\/jats:p>","DOI":"10.1002\/anie.202204851","type":"journal-article","created":{"date-parts":[[2022,4,6]],"date-time":"2022-04-06T06:02:36Z","timestamp":1649224956000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":17,"title":["(PNSiMe\n                    <sub>3<\/sub>\n                    )\n                    <sub>4<\/sub>\n                    (NMe)\n                    <sub>6<\/sub>\n                    : A Robust Tetravalent Phosphaza\u2010adamantane Scaffold for Molecular and Macromolecular Construction**"],"prefix":"10.1002","volume":"61","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-1017-1407","authenticated-orcid":false,"given":"Joseph","family":"Bedard","sequence":"first","affiliation":[{"name":"Chemistry Department Dalhousie University  6274 Coburg Road Halifax Nova Scotia B3H 4R2 Canada"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Nicholas J.","family":"Roberts","sequence":"additional","affiliation":[{"name":"Chemistry Department Dalhousie University  6274 Coburg Road Halifax Nova Scotia B3H 4R2 Canada"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mohsen","family":"Shayan","sequence":"additional","affiliation":[{"name":"Chemistry Department Dalhousie University  6274 Coburg Road Halifax Nova Scotia B3H 4R2 Canada"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8493-4844","authenticated-orcid":false,"given":"Karlee L.","family":"Bamford","sequence":"additional","affiliation":[{"name":"Chemistry Department Dalhousie University  6274 Coburg Road Halifax Nova Scotia B3H 4R2 Canada"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8237-5855","authenticated-orcid":false,"given":"Ulrike","family":"Werner\u2010Zwanziger","sequence":"additional","affiliation":[{"name":"Chemistry Department Dalhousie University  6274 Coburg Road Halifax Nova Scotia B3H 4R2 Canada"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4356-6795","authenticated-orcid":false,"given":"Katherine M.","family":"Marczenko","sequence":"additional","affiliation":[{"name":"Department of Chemistry University of Guelph  Guelph Ontario N1G 2W1 Canada"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9180-7907","authenticated-orcid":false,"given":"Saurabh S.","family":"Chitnis","sequence":"additional","affiliation":[{"name":"Chemistry Department Dalhousie University  6274 Coburg Road Halifax Nova Scotia B3H 4R2 Canada"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2022,4,25]]},"reference":[{"key":"e_1_2_7_1_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja992924w"},{"key":"e_1_2_7_2_1","first-page":"3586","volume":"5","author":"Schilling C. I.","year":"2007","journal-title":"Org. Biomol. Chem."},{"key":"e_1_2_7_3_1","unstructured":"\u00a0"},{"key":"e_1_2_7_4_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja981137g"},{"key":"e_1_2_7_5_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200454234"},{"key":"e_1_2_7_5_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200454234"},{"key":"e_1_2_7_6_2","doi-asserted-by":"publisher","DOI":"10.1002\/adsc.200404207"},{"key":"e_1_2_7_7_2","doi-asserted-by":"publisher","DOI":"10.1002\/adsc.201500949"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1002\/psc.2719"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr100264t"},{"key":"e_1_2_7_10_1","unstructured":"\u00a0"},{"key":"e_1_2_7_11_2","doi-asserted-by":"publisher","DOI":"10.1039\/C4CS00003J"},{"key":"e_1_2_7_12_2","doi-asserted-by":"publisher","DOI":"10.1039\/C3NJ00535F"},{"key":"e_1_2_7_13_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr3002824"},{"key":"e_1_2_7_14_2","doi-asserted-by":"publisher","DOI":"10.1039\/c3ra46951d"},{"key":"e_1_2_7_15_2","doi-asserted-by":"publisher","DOI":"10.1126\/sciadv.aat9180"},{"key":"e_1_2_7_16_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja010825o"},{"key":"e_1_2_7_17_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja045123o"},{"key":"e_1_2_7_18_1","unstructured":"\u00a0"},{"key":"e_1_2_7_19_2","doi-asserted-by":"publisher","DOI":"10.1021\/ma802322j"},{"key":"e_1_2_7_20_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemmater.5b01346"},{"key":"e_1_2_7_21_1","unstructured":"\u00a0"},{"key":"e_1_2_7_22_2","doi-asserted-by":"publisher","DOI":"10.1039\/D0CC00254B"},{"key":"e_1_2_7_23_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.organomet.0c00378"},{"key":"e_1_2_7_24_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201903354"},{"key":"e_1_2_7_24_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201903354"},{"key":"e_1_2_7_25_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201911842"},{"key":"e_1_2_7_25_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201911842"},{"key":"e_1_2_7_26_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201904361"},{"key":"e_1_2_7_27_1","unstructured":"\u00a0"},{"key":"e_1_2_7_28_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja01505a055"},{"key":"e_1_2_7_29_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja01467a019"},{"key":"e_1_2_7_30_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic50006a033"},{"key":"e_1_2_7_31_2","doi-asserted-by":"publisher","DOI":"10.1002\/9780470132395.ch17"},{"key":"e_1_2_7_32_1","unstructured":"\u00a0"},{"key":"e_1_2_7_33_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0020-1693(00)81940-4"},{"key":"e_1_2_7_34_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic50170a028"},{"key":"e_1_2_7_35_2","doi-asserted-by":"publisher","DOI":"10.1080\/00945718308055885"},{"key":"e_1_2_7_36_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic50127a051"},{"key":"e_1_2_7_37_2","doi-asserted-by":"publisher","DOI":"10.1039\/c39720001050"},{"key":"e_1_2_7_38_2","first-page":"1587","author":"Wolff A.","year":"1973","journal-title":"Bull. Soc. Chim. Fr."},{"key":"e_1_2_7_39_1","unstructured":"\u00a0"},{"key":"e_1_2_7_40_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.199108301"},{"key":"e_1_2_7_40_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.19911030723"},{"key":"e_1_2_7_41_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201701084"},{"key":"e_1_2_7_41_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201701084"},{"key":"e_1_2_7_42_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201704305"},{"key":"e_1_2_7_43_1","unstructured":"H. Sato T. Tono T. Shiratori A. Nishida Adeka Corp. Japan2015 p.\u200522."},{"key":"e_1_2_7_44_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja00996a027"},{"key":"e_1_2_7_45_1","unstructured":"Deposition Numbers2128602 and 2128603contain the supplementary crystallographic data for this paper. These data are provided free of charge by the joint Cambridge Crystallographic Data Centre and Fachinformationszentrum KarlsruheAccess Structures service."},{"key":"e_1_2_7_46_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201905439"},{"key":"e_1_2_7_46_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201905439"},{"key":"e_1_2_7_47_1","unstructured":"Y. Kondo H. Naka T. Shimo Tohoku University Japan2010 p.\u200526."},{"key":"e_1_2_7_48_1","first-page":"1437","author":"Martynov I. V.","year":"1987","journal-title":"Izv. Akad. Nauk SSSR Ser. Khim."},{"key":"e_1_2_7_49_1","unstructured":"\u00a0"},{"key":"e_1_2_7_50_2","doi-asserted-by":"publisher","DOI":"10.1139\/v78-044"},{"key":"e_1_2_7_51_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.cplett.2005.05.108"},{"key":"e_1_2_7_52_2","doi-asserted-by":"publisher","DOI":"10.1002\/mrc.2079"},{"key":"e_1_2_7_53_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.8b09063"},{"key":"e_1_2_7_54_1","unstructured":"\u00a0"},{"key":"e_1_2_7_55_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201806235"},{"key":"e_1_2_7_55_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201806235"},{"key":"e_1_2_7_56_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.202001179"},{"key":"e_1_2_7_57_1","unstructured":"\u00a0"},{"key":"e_1_2_7_58_2","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1097-4636(199602)30:2<133::AID-JBM1>3.0.CO;2-S"},{"key":"e_1_2_7_59_2","doi-asserted-by":"publisher","DOI":"10.1039\/c0sm01000f"},{"key":"e_1_2_7_60_2","doi-asserted-by":"publisher","DOI":"10.1002\/mame.202100349"},{"key":"e_1_2_7_61_2","doi-asserted-by":"publisher","DOI":"10.1002\/mabi.201400390"},{"key":"e_1_2_7_62_2","doi-asserted-by":"publisher","DOI":"10.1039\/C6CS00340K"},{"key":"e_1_2_7_63_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202006175"},{"key":"e_1_2_7_63_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.202006175"},{"key":"e_1_2_7_64_2","doi-asserted-by":"publisher","DOI":"10.1021\/cm00045a003"},{"key":"e_1_2_7_65_1","unstructured":"\u00a0"},{"key":"e_1_2_7_66_2","doi-asserted-by":"publisher","DOI":"10.1021\/cm00024a005"},{"key":"e_1_2_7_67_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0925-8388(99)00060-2"},{"key":"e_1_2_7_68_2","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201402356"},{"key":"e_1_2_7_69_1","doi-asserted-by":"publisher","DOI":"10.1021\/ol026152b"},{"key":"e_1_2_7_70_1","unstructured":"\u00a0"},{"key":"e_1_2_7_71_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201605936"},{"key":"e_1_2_7_71_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201605936"},{"key":"e_1_2_7_72_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.ica.2010.08.052"}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.202204851","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/anie.202204851","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.202204851","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,4,10]],"date-time":"2025-04-10T04:06:01Z","timestamp":1744257961000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.202204851"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2022,4,25]]},"references-count":81,"journal-issue":{"issue":"25","published-print":{"date-parts":[[2022,6,20]]}},"alternative-id":["10.1002\/anie.202204851"],"URL":"https:\/\/doi.org\/10.1002\/anie.202204851","archive":["Portico"],"relation":{"has-preprint":[{"id-type":"doi","id":"10.26434\/chemrxiv-2021-rrm10","asserted-by":"object"}]},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2022,4,25]]},"assertion":[{"value":"2022-04-01","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2022-04-25","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e202204851"}}