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This second method tolerates sensitive groups such as an ester, ketone or nitro function. Reaction of these dicarbamoylzincs with allylic, benzylic, aryl, alkenyl bromides, acid chlorides, aldehydes or enones provided various polyfunctional amides in 47\u201397\u2009% yields.<jats:sup>13<\/jats:sup>C NMR characterization of these new carbamoylzinc derivatives is reported.<\/jats:p>","DOI":"10.1002\/anie.202205440","type":"journal-article","created":{"date-parts":[[2022,5,13]],"date-time":"2022-05-13T14:21:32Z","timestamp":1652451692000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":8,"title":["Preparation of Functionalized Amides Using Dicarbamoylzincs"],"prefix":"10.1002","volume":"61","author":[{"given":"Dimitrije","family":"Djukanovic","sequence":"first","affiliation":[{"name":"Department Chemie Ludwig-Maximilians-Universit\u00e4t M\u00fcnchen Butenandtstra\u00dfe 5\u201313, Haus F 81377 M\u00fcnchen Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Maximilian A.","family":"Ganiek","sequence":"additional","affiliation":[{"name":"Patheon, by Thermo Fisher Scientific Patheon Regensburg Gmbh Donaustaufer Stra\u00dfe 378 93055 Regensburg Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kohei","family":"Nishi","sequence":"additional","affiliation":[{"name":"Graduate School of Engineering Science Osaka University 1-3 Machikaneyama Toyonaka 565-0871 Osaka Japan"},{"name":"Graduate School of Pharmaceutical Sciences Osaka University 1-6 Yamadaoka Suita 565-0871 Osaka Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Konstantin","family":"Karaghiosoff","sequence":"additional","affiliation":[{"name":"Department Chemie Ludwig-Maximilians-Universit\u00e4t M\u00fcnchen Butenandtstra\u00dfe 5\u201313, Haus F 81377 M\u00fcnchen Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kazushi","family":"Mashima","sequence":"additional","affiliation":[{"name":"Graduate School of Engineering Science Osaka University 1-3 Machikaneyama Toyonaka 565-0871 Osaka Japan"},{"name":"Graduate School of Pharmaceutical Sciences Osaka University 1-6 Yamadaoka Suita 565-0871 Osaka Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7913-4332","authenticated-orcid":false,"given":"Paul","family":"Knochel","sequence":"additional","affiliation":[{"name":"Department Chemie Ludwig-Maximilians-Universit\u00e4t M\u00fcnchen Butenandtstra\u00dfe 5\u201313, Haus F 81377 M\u00fcnchen Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2022,6,13]]},"reference":[{"key":"e_1_2_3_1_1","volume-title":"Umpoled Synthons","author":"Hase T. 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