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It exists as a dimeric velcraplex in D<jats:sub>2<\/jats:sub>O, but forms host\u2013guest complexes with hydrophobic and amphiphilic guests. Alkanes (C5 to C10), cyclic ketones (C6\u2013C10), cyclic alcohols (C6\u2013C8) and various amphiphilic guests form 1\u2009:\u20091 cavitand complexes. A cyclic array of hydrogen bonds, bridged by solvent\/water (D<jats:sub>2<\/jats:sub>O) molecules, stabilizes the vase conformation of the complexes. With longer alkanes (C12\u2013C15), symmetrical dialkyl amine, urea and phosphate, 2\u2009:\u20091 host:guest capsules are formed. 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