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Here, we challenge this assumption presenting a novel, conceptually different transformation, for which the redshift is continuous. In the room\u2010temperature transformation from CdTe MSC\u2010448 to MSC\u2010488 (designated by the peak wavelengths in nanometer), the redshift of absorption monitored in situ displays distinctly continuous and\/or step\u2010wise behavior. Based on conclusive evidence provided by real\u2010time experiments, the former transformation is apparently direct and intra\u2010cluster with a relatively large energy barrier. The latter transformation is indirect and assisted by MSC precursor compounds (PCs). The former transformation follows the latter often, being predominant at a relatively high temperature. The present findings encourage a reconsideration of the absorption redshift reported previously for transformations of binary II\u2013VI MSCs, together with the pathway associated without the increase of cluster mass.<\/jats:p>","DOI":"10.1002\/anie.202205784","type":"journal-article","created":{"date-parts":[[2022,7,7]],"date-time":"2022-07-07T03:49:15Z","timestamp":1657165755000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":28,"title":["A Real\u2010Time In Situ Demonstration of Direct and Indirect Transformation Pathways in CdTe Magic\u2010Size Clusters at Room Temperature"],"prefix":"10.1002","volume":"61","author":[{"given":"Chaoran","family":"Luan","sequence":"first","affiliation":[{"name":"Laboratory of Ethnopharmacology Tissue-orientated Property of Chinese Medicine Key Laboratory of Sichuan Province West China School of Medicine West China Hospital Sichuan University Chengdu Sichuan, 610065 P. R. 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