{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,30]],"date-time":"2026-10-30T00:40:40Z","timestamp":1793320840436,"version":"4.5.0"},"reference-count":49,"publisher":"Wiley","issue":"35","license":[{"start":{"date-parts":[[2022,7,20]],"date-time":"2022-07-20T00:00:00Z","timestamp":1658275200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2022,8,26]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>LiNi<jats:sub><jats:italic>x<\/jats:italic><\/jats:sub>Co<jats:sub><jats:italic>y<\/jats:italic><\/jats:sub>Mn<jats:sub><jats:italic>z<\/jats:italic><\/jats:sub>O<jats:sub>2<\/jats:sub> (<jats:italic>x<\/jats:italic>+y+<jats:italic>z<\/jats:italic>=1)||graphite lithium\u2010ion battery (LIB) chemistry promises practical applications. However, its low\u2010temperature (\u2264 \u221220\u2009\u00b0C) performance is poor because the increased resistance encountered by Li<jats:sup>+<\/jats:sup> transport in and across the bulk electrolytes and the electrolyte\/electrode interphases induces capacity loss and battery failures. Though tremendous efforts have been made, there is still no effective way to reduce the charge transfer resistance (<jats:italic>R<\/jats:italic><jats:sub>ct<\/jats:sub>) which dominates low\u2010temperature LIBs performance. Herein, we propose a strategy of using low\u2010polarity\u2010solvent electrolytes which have weak interactions between the solvents and the Li<jats:sup>+<\/jats:sup> to reduce <jats:italic>R<\/jats:italic><jats:sub>ct<\/jats:sub>, achieving facile Li<jats:sup>+<\/jats:sup> transport at sub\u2010zero temperatures. The exemplary electrolyte enables LiNi<jats:sub>0.8<\/jats:sub>Mn<jats:sub>0.1<\/jats:sub>Co<jats:sub>0.1<\/jats:sub>O<jats:sub>2<\/jats:sub>||graphite cells to deliver a capacity of \u2248113\u2005mAh\u2009g<jats:sup>\u22121<\/jats:sup> (98\u2009% full\u2010cell capacity) at 25\u2009\u00b0C and to remain 82\u2009% of their room\u2010temperature capacity at \u221220\u2009\u00b0C without lithium plating at 1\/3C. They also retain 84\u2009% of their capacity at \u221230\u2009\u00b0C and 78\u2009% of their capacity at \u221240\u2009\u00b0C and show stable cycling at 50\u2009\u00b0C.<\/jats:p>","DOI":"10.1002\/anie.202205967","type":"journal-article","created":{"date-parts":[[2022,7,5]],"date-time":"2022-07-05T17:03:53Z","timestamp":1657040633000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":224,"title":["Enhancing Li<sup>+<\/sup> Transport in NMC811||Graphite Lithium\u2010Ion Batteries at Low Temperatures by Using Low\u2010Polarity\u2010Solvent Electrolytes"],"prefix":"10.1002","volume":"61","author":[{"given":"Bo","family":"Nan","sequence":"first","affiliation":[{"name":"Department of Chemistry and Biochemistry University of Maryland  College Park MD 20742 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Long","family":"Chen","sequence":"additional","affiliation":[{"name":"Department of Chemical and Biomolecular Engineering University of Maryland  College Park MD 20742 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Nuwanthi D.","family":"Rodrigo","sequence":"additional","affiliation":[{"name":"Department of Chemistry University of Rhode Island  Kingston RI 02881 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Oleg","family":"Borodin","sequence":"additional","affiliation":[{"name":"Battery Science Branch Energy Science Division U.S. Army Combat Capabilities Development Command Army Research Laboratory  Adelphi MD 20783 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Nan","family":"Piao","sequence":"additional","affiliation":[{"name":"Department of Chemical and Biomolecular Engineering University of Maryland  College Park MD 20742 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jiale","family":"Xia","sequence":"additional","affiliation":[{"name":"Department of Chemical and Biomolecular Engineering University of Maryland  College Park MD 20742 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Travis","family":"Pollard","sequence":"additional","affiliation":[{"name":"Battery Science Branch Energy Science Division U.S. Army Combat Capabilities Development Command Army Research Laboratory  Adelphi MD 20783 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Singyuk","family":"Hou","sequence":"additional","affiliation":[{"name":"Department of Chemical and Biomolecular Engineering University of Maryland  College Park MD 20742 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jiaxun","family":"Zhang","sequence":"additional","affiliation":[{"name":"Department of Chemical and Biomolecular Engineering University of Maryland  College Park MD 20742 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiao","family":"Ji","sequence":"additional","affiliation":[{"name":"Department of Chemical and Biomolecular Engineering University of Maryland  College Park MD 20742 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jijian","family":"Xu","sequence":"additional","affiliation":[{"name":"Department of Chemical and Biomolecular Engineering University of Maryland  College Park MD 20742 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiyue","family":"Zhang","sequence":"additional","affiliation":[{"name":"Department of Chemical and Biomolecular Engineering University of Maryland  College Park MD 20742 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lin","family":"Ma","sequence":"additional","affiliation":[{"name":"Department of Mechanical Engineering and Engineering Science The University of North Carolina at Charlotte  Charlotte NC 28223 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xinzi","family":"He","sequence":"additional","affiliation":[{"name":"Department of Chemical and Biomolecular Engineering University of Maryland  College Park MD 20742 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sufu","family":"Liu","sequence":"additional","affiliation":[{"name":"Department of Chemical and Biomolecular Engineering University of Maryland  College Park MD 20742 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hongli","family":"Wan","sequence":"additional","affiliation":[{"name":"Department of Chemical and Biomolecular Engineering University of Maryland  College Park MD 20742 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Enyuan","family":"Hu","sequence":"additional","affiliation":[{"name":"Chemistry Division Brookhaven National Laboratory  Upton NY 11973 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Weiran","family":"Zhang","sequence":"additional","affiliation":[{"name":"Department of Chemical and Biomolecular Engineering University of Maryland  College Park MD 20742 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kang","family":"Xu","sequence":"additional","affiliation":[{"name":"Battery Science Branch Energy Science Division U.S. Army Combat Capabilities Development Command Army Research Laboratory  Adelphi MD 20783 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiao\u2010Qing","family":"Yang","sequence":"additional","affiliation":[{"name":"Chemistry Division Brookhaven National Laboratory  Upton NY 11973 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Brett","family":"Lucht","sequence":"additional","affiliation":[{"name":"Department of Chemistry University of Rhode Island  Kingston RI 02881 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8626-6381","authenticated-orcid":false,"given":"Chunsheng","family":"Wang","sequence":"additional","affiliation":[{"name":"Department of Chemical and Biomolecular Engineering University of Maryland  College Park MD 20742 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2022,7,20]]},"reference":[{"key":"e_1_2_7_1_1","doi-asserted-by":"publisher","DOI":"10.1038\/nenergy.2017.108"},{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1149\/2.1221802jes"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1149\/1.1690782"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9CS00728H"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1557\/jmr.2012.104"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1149\/2.0121903jes"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.201909887"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0378-7753(01)00682-6"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr030203g"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1021\/la901829v"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.aal4263"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0EE01446J"},{"key":"e_1_2_7_13_1","doi-asserted-by":"publisher","DOI":"10.1039\/C3EE43029D"},{"key":"e_1_2_7_14_1","doi-asserted-by":"publisher","DOI":"10.1149\/1.3615828"},{"key":"e_1_2_7_15_1","doi-asserted-by":"publisher","DOI":"10.1021\/la1009994"},{"key":"e_1_2_7_16_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41560-019-0474-3"},{"key":"e_1_2_7_17_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41560-021-00783-z"},{"key":"e_1_2_7_18_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201900266"},{"key":"e_1_2_7_18_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201900266"},{"key":"e_1_2_7_19_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsenergylett.0c01209"},{"key":"e_1_2_7_20_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.joule.2018.01.017"},{"key":"e_1_2_7_21_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202000368"},{"key":"e_1_2_7_22_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsenergylett.1c00484"},{"key":"e_1_2_7_23_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202011482"},{"key":"e_1_2_7_23_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.202011482"},{"key":"e_1_2_7_24_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5CP05121E"},{"key":"e_1_2_7_25_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpcc.5b03694"},{"key":"e_1_2_7_26_1","doi-asserted-by":"publisher","DOI":"10.1149\/2.0511802jes"},{"key":"e_1_2_7_27_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41560-020-0601-1"},{"key":"e_1_2_7_28_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemmater.1c01744"},{"key":"e_1_2_7_29_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.201401792"},{"key":"e_1_2_7_30_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41560-020-0567-z"},{"key":"e_1_2_7_31_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsenergylett.7b00792"},{"key":"e_1_2_7_32_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202017063"},{"key":"e_1_2_7_32_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.202017063"},{"key":"e_1_2_7_33_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.elecom.2018.10.007"},{"key":"e_1_2_7_34_1","doi-asserted-by":"publisher","DOI":"10.1149\/1.2042907"},{"key":"e_1_2_7_35_1","doi-asserted-by":"publisher","DOI":"10.1149\/1.2409866"},{"key":"e_1_2_7_36_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsenergylett.9b00822"},{"key":"e_1_2_7_37_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0TA10166D"},{"key":"e_1_2_7_38_1","doi-asserted-by":"publisher","DOI":"10.1149\/2.1441707jes"},{"key":"e_1_2_7_39_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsenergylett.7b00163"},{"key":"e_1_2_7_40_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.electacta.2017.11.018"},{"key":"e_1_2_7_41_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ensm.2019.12.020"},{"key":"e_1_2_7_42_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja305366r"},{"key":"e_1_2_7_43_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0378-7753(99)00187-1"},{"key":"e_1_2_7_44_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.201903568"},{"key":"e_1_2_7_45_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41560-021-00792-y"},{"key":"e_1_2_7_46_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1TA04737J"}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.202205967","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/anie.202205967","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.202205967","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,8,18]],"date-time":"2023-08-18T02:36:30Z","timestamp":1692326190000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.202205967"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2022,7,20]]},"references-count":49,"journal-issue":{"issue":"35","published-print":{"date-parts":[[2022,8,26]]}},"alternative-id":["10.1002\/anie.202205967"],"URL":"https:\/\/doi.org\/10.1002\/anie.202205967","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2022,7,20]]},"assertion":[{"value":"2022-04-24","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2022-07-20","order":2,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e202205967"}}