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Further reactions with electrophiles (aldehydes, ketones, allylic bromides, aryl halides (Negishi cross\u2010coupling)) furnished a range of polyfunctional fluoro\u2010substituted unsaturated building blocks. Several postfunctionalizations were described as well as NMR\u2010studies confirming the dimeric structure of the base.<\/jats:p>","DOI":"10.1002\/anie.202206176","type":"journal-article","created":{"date-parts":[[2022,5,16]],"date-time":"2022-05-16T15:49:13Z","timestamp":1652716153000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":6,"title":["Regioselective Magnesiations of Fluorinated Arenes and Heteroarenes Using Magnesium\u2010<i>bis<\/i>\u2010Diisopropylamide (MBDA) in Hydrocarbons"],"prefix":"10.1002","volume":"61","author":[{"given":"Andreas","family":"Hess","sequence":"first","affiliation":[{"name":"Department Chemie Ludwig-Maximilians-Universit\u00e4t M\u00fcnchen Butenandtstrasse 5\u201313, Haus F 81377 M\u00fcnchen Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Nurtalya","family":"Alandini","sequence":"additional","affiliation":[{"name":"Department Chemie Ludwig-Maximilians-Universit\u00e4t M\u00fcnchen Butenandtstrasse 5\u201313, Haus F 81377 M\u00fcnchen Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yusuf C.","family":"Guersoy","sequence":"additional","affiliation":[{"name":"Department Chemie Ludwig-Maximilians-Universit\u00e4t M\u00fcnchen Butenandtstrasse 5\u201313, Haus F 81377 M\u00fcnchen Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7913-4332","authenticated-orcid":false,"given":"Paul","family":"Knochel","sequence":"additional","affiliation":[{"name":"Department Chemie Ludwig-Maximilians-Universit\u00e4t M\u00fcnchen Butenandtstrasse 5\u201313, Haus F 81377 M\u00fcnchen Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2022,6]]},"reference":[{"key":"e_1_2_3_1_1","unstructured":"\u00a0"},{"key":"e_1_2_3_2_2","doi-asserted-by":"publisher","DOI":"10.1039\/B610213C"},{"key":"e_1_2_3_3_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jmedchem.5b00258"},{"key":"e_1_2_3_4_1","doi-asserted-by":"publisher","DOI":"10.1021\/jm800219f"},{"key":"e_1_2_3_5_1","unstructured":"\u00a0"},{"key":"e_1_2_3_6_2","doi-asserted-by":"publisher","DOI":"10.1038\/nature10108"},{"key":"e_1_2_3_7_2","doi-asserted-by":"publisher","DOI":"10.1007\/978-3-642-25103-0"},{"key":"e_1_2_3_8_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.aaz2258"},{"key":"e_1_2_3_9_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202113727"},{"key":"e_1_2_3_9_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.202113727"},{"key":"e_1_2_3_10_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202115467"},{"key":"e_1_2_3_10_3","doi-asserted-by":"crossref","first-page":"e202115467","DOI":"10.1002\/ange.202115467","volume":"134","year":"2022","journal-title":"Angew. 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