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Key steps of this reaction involve activation of the carbon\u2013silicon bond of an acylsilane by a chiral N\u2010heterocyclic carbene (NHC) catalyst to form a silyl acyl anion intermediate. These acyl anions then undergo an addition reaction with indole aldehydes in a highly chemo\u2010 and enantioselective manner to afford \u03b1\u2010silyloxy ketones with excellent optical purities. The reaction mechanism of this cross Brook\u2013Benzoin reaction was investigated through both experimental and computational methods. The chiral \u03b1\u2010hydroxy ketone derivatives obtained by this approach show promising, agrochemically interesting activity against harmful plant bacteria.<\/jats:p>","DOI":"10.1002\/anie.202206961","type":"journal-article","created":{"date-parts":[[2022,6,13]],"date-time":"2022-06-13T17:13:57Z","timestamp":1655140437000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":24,"title":["Carbene\u2010Catalyzed Activation of C\u2212Si Bonds for Chemo\u2010 and Enantioselective Cross Brook\u2013Benzoin Reaction"],"prefix":"10.1002","volume":"61","author":[{"given":"Chenghao","family":"Tang","sequence":"first","affiliation":[{"name":"State Key Laboratory Breeding Base of Green Pesticide and Agricultural Bioengineering Key Laboratory of Green Pesticide and Agricultural Bioengineering Ministry of Education Guizhou University  Guiyang 550025 China"},{"name":"School of Life and Health Science Kaili University  Kaili 556011 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