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Zr\u2010bptc (H\n                    <jats:sub>4<\/jats:sub>\n                    bptc=biphenyl\u20103,3\u2032,5,5\u2032\u2010tetracarboxylic acid) shows a high SO\n                    <jats:sub>2<\/jats:sub>\n                    uptake of 6.2\u2005mmol\u2009g\n                    <jats:sup>\u22121<\/jats:sup>\n                    at 0.1\u2005bar and 298\u2005K, reflecting excellent capture capability and removal of SO\n                    <jats:sub>2<\/jats:sub>\n                    at low concentration (2500\u2005ppm). Dynamic breakthrough experiments confirm that the introduction of amine, atomically\u2010dispersed Cu\n                    <jats:sup>II<\/jats:sup>\n                    or heteroatomic sulphur sites into the pores enhance the capture of SO\n                    <jats:sub>2<\/jats:sub>\n                    at low concentrations. The captured SO\n                    <jats:sub>2<\/jats:sub>\n                    can be converted quantitatively to a pharmaceutical intermediate, aryl N\u2010aminosulfonamide, thus converting waste to chemical values. In situ X\u2010ray diffraction, infrared micro\u2010spectroscopy and inelastic neutron scattering enable the visualisation of the binding domains of adsorbed SO\n                    <jats:sub>2<\/jats:sub>\n                    molecules and host\u2013guest binding dynamics in these materials at the atomic level. Refinement of the pore environment plays a critical role in designing efficient sorbent materials.\n                  <\/jats:p>","DOI":"10.1002\/anie.202207259","type":"journal-article","created":{"date-parts":[[2022,6,23]],"date-time":"2022-06-23T05:49:27Z","timestamp":1655963367000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":54,"title":["Structural and Dynamic Analysis of Sulphur Dioxide Adsorption in a Series of Zirconium\u2010Based Metal\u2013Organic Frameworks"],"prefix":"10.1002","volume":"61","author":[{"given":"Jiangnan","family":"Li","sequence":"first","affiliation":[{"name":"Department of Chemistry University of Manchester  Manchester M13 9PL UK"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Gemma L.","family":"Smith","sequence":"additional","affiliation":[{"name":"Department of Chemistry University of Manchester  Manchester M13 9PL UK"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yinlin","family":"Chen","sequence":"additional","affiliation":[{"name":"Department of Chemistry University of Manchester  Manchester M13 9PL UK"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yujie","family":"Ma","sequence":"additional","affiliation":[{"name":"Department of Chemistry University of Manchester  Manchester M13 9PL UK"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Meredydd","family":"Kippax\u2010Jones","sequence":"additional","affiliation":[{"name":"Department of Chemistry University of Manchester  Manchester M13 9PL UK"},{"name":"Diamond of Light Source  Harwell Science Campus Oxfordshire OX11 0DE UK"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mengtian","family":"Fan","sequence":"additional","affiliation":[{"name":"Department of Chemistry University of Manchester  Manchester M13 9PL UK"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wanpeng","family":"Lu","sequence":"additional","affiliation":[{"name":"Department of Chemistry University of Manchester  Manchester M13 9PL UK"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mark D.","family":"Frogley","sequence":"additional","affiliation":[{"name":"Diamond of Light Source  Harwell Science Campus Oxfordshire OX11 0DE UK"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Gianfelice","family":"Cinque","sequence":"additional","affiliation":[{"name":"Diamond of Light Source  Harwell Science Campus Oxfordshire OX11 0DE UK"},{"name":"Department of Engineering Sciences University of Oxford  Oxford OX1 3PJ UK"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sarah J.","family":"Day","sequence":"additional","affiliation":[{"name":"Diamond of Light Source  Harwell Science Campus Oxfordshire OX11 0DE UK"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Stephen P.","family":"Thompson","sequence":"additional","affiliation":[{"name":"Diamond of Light Source  Harwell Science Campus Oxfordshire OX11 0DE UK"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yongqiang","family":"Cheng","sequence":"additional","affiliation":[{"name":"Neutron Scattering Division Oak Ridge National Laboratory  Oak Ridge TN 37831 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Luke L.","family":"Daemen","sequence":"additional","affiliation":[{"name":"Neutron Scattering Division Oak Ridge National Laboratory  Oak Ridge TN 37831 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Anibal J.","family":"Ramirez\u2010Cuesta","sequence":"additional","affiliation":[{"name":"Neutron Scattering Division Oak Ridge National Laboratory  Oak Ridge TN 37831 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6992-0700","authenticated-orcid":false,"given":"Martin","family":"Schr\u00f6der","sequence":"additional","affiliation":[{"name":"Department of Chemistry University of Manchester  Manchester M13 9PL UK"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sihai","family":"Yang","sequence":"additional","affiliation":[{"name":"Department of Chemistry University of Manchester  Manchester M13 9PL UK"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2022,7,25]]},"reference":[{"key":"e_1_2_8_1_1","volume-title":"Sulfur Dioxide, Vol.\u200535","author":"Muller H.","year":"2012"},{"key":"e_1_2_8_2_1","unstructured":"U.S. Energy Information Administration. International Energy Outlook 2019;"},{"key":"e_1_2_8_2_2","unstructured":"U.S. Energy Information Administration: Washington DC 2019."},{"key":"e_1_2_8_3_1","unstructured":"European Environment Agency (EEA). Sulphur dioxide (SO2) emissions. Indicator codes: APE 001 https:\/\/www.eea.europa.eu\/data-and-maps\/indicators\/eea-32-sulphur-dioxide-so2-emissions-1 2015. (Accessed October 2019)."},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-018-06885-9"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-019-11387-3"},{"key":"e_1_2_8_6_1","unstructured":"Editorial Nat. 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