{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,5,14]],"date-time":"2026-05-14T00:23:18Z","timestamp":1778718198648,"version":"3.51.4"},"reference-count":80,"publisher":"Wiley","issue":"36","license":[{"start":{"date-parts":[[2022,8,4]],"date-time":"2022-08-04T00:00:00Z","timestamp":1659571200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by-nc-nd\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100001659","name":"Deutsche Forschungsgemeinschaft","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100001659","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2022,9,5]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>H<jats:sub>2<\/jats:sub> adds reversibly across the metal\u2010metal bond of [(BDI)Ga(H)\u2212Zn(tmeda)(thf)][BAr<jats:sub>4<\/jats:sub><jats:sup>F<\/jats:sup>] (BDI=[HC{C(CH<jats:sub>3<\/jats:sub>)N(2,6\u2010<jats:italic>i<\/jats:italic>Pr<jats:sub>2<\/jats:sub>\u2010C<jats:sub>6<\/jats:sub>H<jats:sub>3<\/jats:sub>)}<jats:sub>2<\/jats:sub>]<jats:sup>\u2212<\/jats:sup>, TMEDA=<jats:italic>N<\/jats:italic>,<jats:italic>N<\/jats:italic>,<jats:italic>N\u2032<\/jats:italic>,<jats:italic>N\u2032<\/jats:italic>\u2010tetramethylethylenediamine, BAr<jats:sub>4<\/jats:sub><jats:sup>F\u2212<\/jats:sup>=[B(C<jats:sub>6<\/jats:sub>H<jats:sub>3<\/jats:sub>\u20103,5\u2010(CF<jats:sub>3<\/jats:sub>)<jats:sub>2<\/jats:sub>)<jats:sub>4<\/jats:sub>]<jats:sup>\u2212<\/jats:sup>). Due to the stabilising effect of solvent coordination, hydrogenation products [(BDI)GaH<jats:sub>2<\/jats:sub>] and [(tmeda)ZnH(thf)][BAr<jats:sub>4<\/jats:sub><jats:sup>F<\/jats:sup>] are favoured in THF solution, but THF\u2010free mixtures of [(BDI)GaH<jats:sub>2<\/jats:sub>] and [(tmeda)ZnH(OEt<jats:sub>2<\/jats:sub>)][BAr<jats:sub>4<\/jats:sub><jats:sup>F<\/jats:sup>] are predisposed towards entropically driven dehydrogenation to [(BDI)Ga(H)\u2212Zn(tmeda)][BAr<jats:sub>4<\/jats:sub><jats:sup>F<\/jats:sup>] in fluorobenzene solution.<\/jats:p>","DOI":"10.1002\/anie.202208855","type":"journal-article","created":{"date-parts":[[2022,7,14]],"date-time":"2022-07-14T12:40:43Z","timestamp":1657802443000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":11,"title":["Solvent\u2010Dependent Oxidative Addition and Reductive Elimination of H<sub>2<\/sub> Across a Gallium\u2010Zinc Bond"],"prefix":"10.1002","volume":"61","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-2363-4498","authenticated-orcid":false,"given":"Louis J.","family":"Morris","sequence":"first","affiliation":[{"name":"Institute for Inorganic Chemistry RWTH Aachen University  52062 Aachen Germany"},{"name":"Chemistry Research Laboratory University of Oxford  Oxford OX1 3TA UK"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Thayalan","family":"Rajeshkumar","sequence":"additional","affiliation":[{"name":"CNRS INSA UPS UMR 5215 LPCNO Universit\u00e9 de Toulouse  135 Avenue de Rangueil 31077 Toulouse France"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Akira","family":"Okumura","sequence":"additional","affiliation":[{"name":"Institute for Inorganic Chemistry RWTH Aachen University  52062 Aachen 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