{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,28]],"date-time":"2026-09-28T22:10:27Z","timestamp":1790633427401,"version":"4.1.0"},"reference-count":174,"publisher":"Wiley","issue":"40","license":[{"start":{"date-parts":[[2022,8,24]],"date-time":"2022-08-24T00:00:00Z","timestamp":1661299200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["21971066, 22171088"],"award-info":[{"award-number":["21971066, 22171088"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100007219","name":"Natural Science Foundation of Shanghai","doi-asserted-by":"publisher","award":["18JC1412300"],"award-info":[{"award-number":["18JC1412300"]}],"id":[{"id":"10.13039\/100007219","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2022,10,4]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    An asymmetric\n                    <jats:italic>para\u2010<\/jats:italic>\n                    C(sp\n                    <jats:sup>2<\/jats:sup>\n                    )\u2212H bond functionalization of alkyl benzene derivatives was successfully developed via cooperative catalysis of gold and chiral phosphoric acid (CPA), leading to synthetically useful chiral 1,1\u2010diaryl motifs. Chiral phosphoric acid, ligand, and molecular sieves were found to be crucial for enantioselectivity control of this transformation. The salient features of this protocol include mild conditions, high efficiency, commercially available starting materials, highly chemo\u2010 and site\u2010 as well as enantioselective aromatic C\u2212H functionalization, broad substrate scope, and extensive applications of the chiral products. The mechanistic studies suggested that two CPAs might be involved in chiral induction.\n                  <\/jats:p>","DOI":"10.1002\/anie.202208874","type":"journal-article","created":{"date-parts":[[2022,8,3]],"date-time":"2022-08-03T22:29:30Z","timestamp":1659565770000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":44,"title":["Enantioselective\n                    <i>para<\/i>\n                    \u2010C(sp\n                    <sup>2<\/sup>\n                    )\u2212H Functionalization of Alkyl Benzene Derivatives via Cooperative Catalysis of Gold\/Chiral Br\u00f8nsted Acid**"],"prefix":"10.1002","volume":"61","author":[{"given":"Xun\u2010Shen","family":"Liu","sequence":"first","affiliation":[{"name":"School of Chemistry and Molecular Engineering East China Normal University  500 Dongchuan Road Shanghai 200241 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhiqiong","family":"Tang","sequence":"additional","affiliation":[{"name":"School of Chemistry and Molecular Engineering East China Normal University  500 Dongchuan Road Shanghai 200241 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhi\u2010Yao","family":"Si","sequence":"additional","affiliation":[{"name":"School of Chemistry and Molecular Engineering East China Normal University  500 Dongchuan Road Shanghai 200241 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhikun","family":"Zhang","sequence":"additional","affiliation":[{"name":"School of Chemistry and Molecular Engineering East China Normal University  500 Dongchuan Road Shanghai 200241 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lei","family":"Zhao","sequence":"additional","affiliation":[{"name":"School of Chemistry and Molecular Engineering East China Normal University  500 Dongchuan Road Shanghai 200241 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2151-891X","authenticated-orcid":false,"given":"Lu","family":"Liu","sequence":"additional","affiliation":[{"name":"School of Chemistry and Molecular Engineering East China Normal University  500 Dongchuan Road Shanghai 200241 P. R. China"},{"name":"Shanghai Engineering Research Center of Molecular Therapeutics and New Drug Development East China Normal University  3663N Zhongshan Road Shanghai 200062 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2022,8,24]]},"reference":[{"key":"e_1_2_7_1_1","unstructured":"For selected reviews see:"},{"key":"e_1_2_7_2_2","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.1607"},{"key":"e_1_2_7_3_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5b08707"},{"key":"e_1_2_7_4_2","doi-asserted-by":"publisher","DOI":"10.1039\/c1cs15013h"},{"key":"e_1_2_7_5_2","doi-asserted-by":"publisher","DOI":"10.1039\/c0cs00182a"},{"key":"e_1_2_7_6_2","doi-asserted-by":"publisher","DOI":"10.1039\/C8CS00716K"},{"key":"e_1_2_7_7_2","doi-asserted-by":"publisher","DOI":"10.1021\/acsmaterialslett.0c00206"},{"key":"e_1_2_7_8_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202001224"},{"key":"e_1_2_7_8_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.202001224"},{"key":"e_1_2_7_9_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201812116"},{"key":"e_1_2_7_9_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201812116"},{"key":"e_1_2_7_10_1","unstructured":"For selected reviews see:"},{"key":"e_1_2_7_11_2","doi-asserted-by":"publisher","DOI":"10.1039\/b816707a"},{"key":"e_1_2_7_12_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5b12964"},{"key":"e_1_2_7_13_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.6b00692"},{"key":"e_1_2_7_14_2","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.0c03743"},{"key":"e_1_2_7_15_1","unstructured":"For selected reviews see:"},{"key":"e_1_2_7_16_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200301679"},{"key":"e_1_2_7_16_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200301679"},{"key":"e_1_2_7_17_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr078372e"},{"key":"e_1_2_7_18_2","doi-asserted-by":"publisher","DOI":"10.1039\/b817310a"},{"key":"e_1_2_7_19_1","unstructured":"For reviews see ref.\u2005[2]. 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