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Similarly, the reaction of chloro(imino)stannylene [IPrNSnCl]<jats:sub>2<\/jats:sub>with Na<jats:sub>2<\/jats:sub>Fe(CO)<jats:sub>4<\/jats:sub>(1\u2005equiv) resulted in the Fe(CO)<jats:sub>4<\/jats:sub>\u2010bridged bis(stannylene) complex<jats:bold>4<\/jats:bold>. We observed reversible formation of bis(tetrylene) and tetrylene\u2010tetrylone character in complexes<jats:bold>3<\/jats:bold>vs.<jats:bold>5<\/jats:bold>and<jats:bold>4<\/jats:bold>vs.<jats:bold>6<\/jats:bold>, which was supported by DFT calculations. Moreover, the Li\/Sn\/Fe trimetallic complex<jats:bold>12<\/jats:bold>has been isolated from the reaction of [IPrNSnCl]<jats:sub>2<\/jats:sub>with cyclopentadienyl iron dicarbonyl anion. The computational analysis further rationalizes the reduction pathway from these chlorotetrylenes to the corresponding complexes.<\/jats:p>","DOI":"10.1002\/anie.202208930","type":"journal-article","created":{"date-parts":[[2022,8,4]],"date-time":"2022-08-04T15:43:33Z","timestamp":1659627813000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":20,"title":["Isolation and Reactivity of Tetrylene\u2010Tetrylone\u2010Iron Complexes Supported by Bis(<i>N<\/i>\u2010Heterocyclic Imine) Ligands"],"prefix":"10.1002","volume":"61","author":[{"given":"Xuan\u2010Xuan","family":"Zhao","sequence":"first","affiliation":[{"name":"School of Natural Sciences Department of Chemistry WACKER-Institute of Silicon Chemistry and Catalysis Research Center Technische Universit\u00e4t M\u00fcnchen Lichtenbergstra\u00dfe 4 85748 Garching bei M\u00fcnchen 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