{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,30]],"date-time":"2026-10-30T02:04:18Z","timestamp":1793325858313,"version":"4.5.0"},"reference-count":50,"publisher":"Wiley","issue":"43","license":[{"start":{"date-parts":[[2022,9,21]],"date-time":"2022-09-21T00:00:00Z","timestamp":1663718400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22225606, 22176029, 21822601"],"award-info":[{"award-number":["22225606, 22176029, 21822601"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100012226","name":"Fundamental Research Funds for the Central Universities","doi-asserted-by":"publisher","award":["ZYGX2019Z021"],"award-info":[{"award-number":["ZYGX2019Z021"]}],"id":[{"id":"10.13039\/501100012226","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2022,10,24]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    The nitrogen oxides (NOx) formed by photochemical reaction of surface nitrates raise significant concerns. However, little is known about the effect of visible light (&gt;380\u2005nm) on nitrate decomposition and the reaction mechanism. Herein, the decomposition of surface nitrates is investigated under visible light. The results indicate that visible light photocatalysis contributes significantly to nitrate decomposition. Monodentate nitrate (m\u2010NO\n                    <jats:sub>3<\/jats:sub>\n                    <jats:sup>\u2212<\/jats:sup>\n                    ) can be decomposed into NOx by photogenerated electrons starting from the weakly coordinated N\u2212O bond. Water vapor promotes NOx generation because more stable bidentate nitrate (b\u2010NO\n                    <jats:sub>3<\/jats:sub>\n                    <jats:sup>\u2212<\/jats:sup>\n                    ) will be converted into m\u2010NO\n                    <jats:sub>3<\/jats:sub>\n                    <jats:sup>\u2212<\/jats:sup>\n                    by surface hydroxyl groups through hydrogen bonding interactions. Alternatively, b\u2010NO\n                    <jats:sub>3<\/jats:sub>\n                    <jats:sup>\u2212<\/jats:sup>\n                    can be directly decomposed to NO\n                    <jats:sub>2<\/jats:sub>\n                    <jats:sup>\u2212<\/jats:sup>\n                    by NO attack, but this process is subject to photocatalytic oxidation. This work brings a new focus on the atmospheric NOx sources and provides a more nuanced understanding of nitrates decomposition processes.\n                  <\/jats:p>","DOI":"10.1002\/anie.202209201","type":"journal-article","created":{"date-parts":[[2022,8,19]],"date-time":"2022-08-19T05:23:45Z","timestamp":1660886625000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":42,"title":["Insight into the Overlooked Photochemical Decomposition of Atmospheric Surface Nitrates Triggered by Visible Light"],"prefix":"10.1002","volume":"61","author":[{"given":"Hong","family":"Wang","sequence":"first","affiliation":[{"name":"Research Center for Environmental and Energy Catalysis Institute of Fundamental and Frontier Sciences University of Electronic Science and Technology of China  Chengdu 611731 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yanjuan","family":"Sun","sequence":"additional","affiliation":[{"name":"School of Resources and Environmental University of Electronic Science and Technology of China  Chengdu 611731 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2890-9964","authenticated-orcid":false,"given":"Fan","family":"Dong","sequence":"additional","affiliation":[{"name":"Research Center for Environmental and Energy Catalysis Institute of Fundamental and Frontier Sciences University of Electronic Science and Technology of China  Chengdu 611731 P. R. 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