{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,31]],"date-time":"2026-08-31T12:08:26Z","timestamp":1788178106058,"version":"build-2803163510"},"reference-count":56,"publisher":"Wiley","issue":"37","license":[{"start":{"date-parts":[[2022,8,8]],"date-time":"2022-08-08T00:00:00Z","timestamp":1659916800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100001659","name":"Deutsche Forschungsgemeinschaft","doi-asserted-by":"publisher","award":["UniSysCat"],"award-info":[{"award-number":["UniSysCat"]}],"id":[{"id":"10.13039\/501100001659","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2022,9,12]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>White phosphorus (P<jats:sub>4<\/jats:sub>) undergoes degradation to P<jats:sub>2<\/jats:sub>moieties if exposed to the new<jats:italic>N,N<\/jats:italic>\u2010bis(silylenyl)aniline PhN<jats:bold>Si<\/jats:bold><jats:sub>2<\/jats:sub><jats:bold>1<\/jats:bold>(<jats:bold>Si<\/jats:bold>=Si[N(<jats:italic>t<\/jats:italic>Bu)]<jats:sub>2<\/jats:sub>CPh), furnishing the first isolable 2,5\u2010disila\u20103,4\u2010diphosphapyrrole<jats:bold>2<\/jats:bold>and the two novel functionalized Si=P doubly bonded compounds<jats:bold>3<\/jats:bold>and<jats:bold>4<\/jats:bold>. The pathways for the transformation of the non\u2010aromatic 2,5\u2010disila\u20103,4\u2010diphosphapyrrole PhN<jats:bold>Si<\/jats:bold><jats:sub>2<\/jats:sub>P<jats:sub>2<\/jats:sub><jats:bold>2<\/jats:bold>into<jats:bold>3<\/jats:bold>and<jats:bold>4<\/jats:bold>could be uncovered. It became evident that<jats:bold>2<\/jats:bold>reacts readily with both reactants P<jats:sub>4<\/jats:sub>and<jats:bold>1<\/jats:bold>to afford either the polycyclic Si=P\u2010containing product [PhN<jats:bold>Si<\/jats:bold><jats:sub>2<\/jats:sub>P<jats:sub>2<\/jats:sub>]<jats:sub>2<\/jats:sub>P<jats:sub>2<\/jats:sub><jats:bold>3<\/jats:bold>or the unprecedented conjugated<jats:bold>Si<\/jats:bold>=P\u2212<jats:bold>Si<\/jats:bold>=P\u2212<jats:bold>Si<\/jats:bold>=NPh chain\u2010containing compound<jats:bold>4<\/jats:bold>, depending on the employed molar ratio of<jats:bold>1<\/jats:bold>and P<jats:sub>4<\/jats:sub>as well as the reaction conditions. Compounds<jats:bold>3<\/jats:bold>and<jats:bold>4<\/jats:bold>can be converted into each other by reactions with<jats:bold>1<\/jats:bold>and P<jats:sub>4<\/jats:sub>, respectively. All new compounds<jats:bold>1<\/jats:bold>\u2013<jats:bold>4<\/jats:bold>were unequivocally characterized including by single\u2010crystal X\u2010ray diffraction analysis. In addition, the electronic structures of<jats:bold>2<\/jats:bold>\u2013<jats:bold>4<\/jats:bold>were established by Density Functional Theory (DFT) calculations.<\/jats:p>","DOI":"10.1002\/anie.202209250","type":"journal-article","created":{"date-parts":[[2022,7,25]],"date-time":"2022-07-25T10:59:15Z","timestamp":1658746755000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":34,"title":["An Isolable 2,5\u2010Disila\u20103,4\u2010Diphosphapyrrole and a Conjugated Si=P\u2212Si=P\u2212Si=N Chain Through Degradation of White Phosphorus with a<i>N,N<\/i>\u2010Bis(Silylenyl)Aniline"],"prefix":"10.1002","volume":"61","author":[{"given":"Yun","family":"Xiong","sequence":"first","affiliation":[{"name":"Department of Chemistry: Metalorganic and Inorganic Materials Technische Universit\u00e4t Berlin Strasse des 17. Juni 135, Sekr. C2 10623 Berlin Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shicheng","family":"Dong","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Physical Chemistry of Solid Surface and Collaborative Innovation Center of Chemistry for Energy Materials (iChEM) and College of Chemistry and Chemical Engineering Xiamen University Xiamen 361005 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shenglai","family":"Yao","sequence":"additional","affiliation":[{"name":"Department of Chemistry: Metalorganic and Inorganic Materials Technische Universit\u00e4t Berlin Strasse des 17. Juni 135, Sekr. C2 10623 Berlin Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chenshu","family":"Dai","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Physical Chemistry of Solid Surface and Collaborative Innovation Center of Chemistry for Energy Materials (iChEM) and College of Chemistry and Chemical Engineering Xiamen University Xiamen 361005 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jun","family":"Zhu","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Physical Chemistry of Solid Surface and Collaborative Innovation Center of Chemistry for Energy Materials (iChEM) and College of Chemistry and Chemical Engineering Xiamen University Xiamen 361005 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sebastian","family":"Kemper","sequence":"additional","affiliation":[{"name":"Department of Chemistry: Metalorganic and Inorganic Materials Technische Universit\u00e4t Berlin Strasse des 17. Juni 135, Sekr. C2 10623 Berlin Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9873-4103","authenticated-orcid":false,"given":"Matthias","family":"Driess","sequence":"additional","affiliation":[{"name":"Department of Chemistry: Metalorganic and Inorganic Materials Technische Universit\u00e4t Berlin Strasse des 17. Juni 135, Sekr. C2 10623 Berlin Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2022,8,8]]},"reference":[{"key":"e_1_2_7_1_1","unstructured":"\u00a0"},{"key":"e_1_2_7_2_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.214.4527.1343"},{"key":"e_1_2_7_3_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00405a054"},{"key":"e_1_2_7_4_1","unstructured":"\u00a0"},{"key":"e_1_2_7_5_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr100133q"},{"key":"e_1_2_7_6_2","doi-asserted-by":"publisher","DOI":"10.1021\/ar2000875"},{"key":"e_1_2_7_7_2","doi-asserted-by":"publisher","DOI":"10.1002\/cctc.201501015"},{"key":"e_1_2_7_8_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.7b00572"},{"key":"e_1_2_7_9_2","doi-asserted-by":"publisher","DOI":"10.1002\/cctc.201800963"},{"key":"e_1_2_7_10_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.aau5105"},{"key":"e_1_2_7_11_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.202002939"},{"key":"e_1_2_7_12_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201700829"},{"key":"e_1_2_7_13_1","unstructured":"\u00a0"},{"key":"e_1_2_7_14_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0040-4039(01)81351-4"},{"key":"e_1_2_7_15_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00061a034"},{"key":"e_1_2_7_16_1","unstructured":"\u00a0"},{"key":"e_1_2_7_17_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.199110221"},{"key":"e_1_2_7_17_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.19911030814"},{"key":"e_1_2_7_18_2","doi-asserted-by":"publisher","DOI":"10.1039\/C39950000253"},{"key":"e_1_2_7_19_2","doi-asserted-by":"publisher","DOI":"10.1021\/om9508851"},{"key":"e_1_2_7_20_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201105610"},{"key":"e_1_2_7_20_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201105610"},{"key":"e_1_2_7_21_1","doi-asserted-by":"crossref","first-page":"e20220535","DOI":"10.1002\/anie.202116635","volume":"61","author":"Xiong Y.","year":"2022","journal-title":"Angew. Chem. Int. Ed."},{"key":"e_1_2_7_21_2","first-page":"e2022053","volume":"134","year":"2022","journal-title":"Angew. Chem."},{"key":"e_1_2_7_22_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200701203"},{"key":"e_1_2_7_22_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200701203"},{"key":"e_1_2_7_23_1","unstructured":"\u00a0"},{"key":"e_1_2_7_24_2","doi-asserted-by":"publisher","DOI":"10.31635\/ccschem.022.202101709"},{"key":"e_1_2_7_25_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.202201031"},{"key":"e_1_2_7_26_1","unstructured":"\u00a0"},{"key":"e_1_2_7_27_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201005866"},{"key":"e_1_2_7_27_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201005866"},{"key":"e_1_2_7_28_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200902995"},{"key":"e_1_2_7_28_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200902995"},{"key":"e_1_2_7_29_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41557-020-0518-0"},{"key":"e_1_2_7_30_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b07167"},{"key":"e_1_2_7_31_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201606979"},{"key":"e_1_2_7_31_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201606979"},{"key":"e_1_2_7_32_1","unstructured":"\u00a0"},{"key":"e_1_2_7_33_2","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.617"},{"key":"e_1_2_7_34_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja807828t"},{"key":"e_1_2_7_35_1","unstructured":"\u00a0"},{"key":"e_1_2_7_36_2","doi-asserted-by":"publisher","DOI":"10.1002\/hlca.19640470217"},{"key":"e_1_2_7_37_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200600647"},{"key":"e_1_2_7_37_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200600647"},{"key":"e_1_2_7_38_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja106458p"},{"key":"e_1_2_7_39_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201801220"},{"key":"e_1_2_7_40_1","doi-asserted-by":"publisher","DOI":"10.1002\/wcms.1469"},{"key":"e_1_2_7_41_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja077296u"},{"key":"e_1_2_7_42_1","unstructured":"\u00a0"},{"key":"e_1_2_7_43_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.198910381"},{"key":"e_1_2_7_43_3","doi-asserted-by":"crossref","first-page":"1087","DOI":"10.1002\/ange.19891010837","volume":"101","year":"1989","journal-title":"Angew. Chem."},{"key":"e_1_2_7_44_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201609899"},{"key":"e_1_2_7_44_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201609899"},{"key":"e_1_2_7_45_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b05318"},{"key":"e_1_2_7_46_1","unstructured":"Deposition Numbers2175471 (for1) 2175474 (for2) 2175473 (for3) and 2175472 (for4)contain the supplementary crystallographic data for this paper. These data are provided free of charge by the joint Cambridge Crystallographic Data Centre and Fachinformationszentrum KarlsruheAccess Structures service."}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.202209250","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/anie.202209250","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.202209250","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,11,24]],"date-time":"2023-11-24T23:00:10Z","timestamp":1700866810000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.202209250"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2022,8,8]]},"references-count":56,"journal-issue":{"issue":"37","published-print":{"date-parts":[[2022,9,12]]}},"alternative-id":["10.1002\/anie.202209250"],"URL":"https:\/\/doi.org\/10.1002\/anie.202209250","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2022,8,8]]},"assertion":[{"value":"2022-06-24","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2022-08-08","order":2,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e202209250"}}