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Here, we present the synthesis, characterization, and catalytic activity in the one\u2010pot multicomponent Strecker reaction with ketones of three new MOFs prepared with the combination of indium or bismuth and 4,4\u2032,4\u2032\u2032,4\u2032\u2032\u2032\u2010methanetetrayltetrabenzoic acid. One of them, denoted BiPF\u20107, is very robust and chemically stable, and demonstrates a high activity in the formation of the desired \u03b1\u2010aminonitriles. The interaction of the catalytic substrates with the metal centers in this MOF has been crystallographically characterized, showcasing a concerted framework adaptability process that involves structural changes in framework components that are not directly involved in the binding of the guests.<\/jats:p>","DOI":"10.1002\/anie.202209335","type":"journal-article","created":{"date-parts":[[2022,7,16]],"date-time":"2022-07-16T15:33:31Z","timestamp":1657985611000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":28,"title":["Framework Adaptability and Concerted Structural Response in a Bismuth Metal\u2010Organic Framework Catalyst."],"prefix":"10.1002","volume":"61","author":[{"given":"Eloy P.","family":"G\u00f3mez\u2010Oliveira","sequence":"first","affiliation":[{"name":"Materials Science Institute of Madrid, ICMM Spanish National Research Council, CSIC  Sor Juana In\u00e9s de la Cruz, 3 28049 Madrid 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