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Here, we selected the high\u2010capacity carbonyl compound of chloranilic acid (CA) as organic ligand to coordinate with the high\u2010voltage Cu<jats:sup>2+<\/jats:sup> as transition metal node and successfully synthesized copper(II) chloranilate (CuCA) with \u03c0\u2013d conjugation, layered structure and monocrystalline nature. The resulting CuCA presents inorganic and organic redox centers, high electronic conductivity and fast Li<jats:sup>+<\/jats:sup> diffusion kinetics, leading to high discharge capacity (297.0\u2005mAh\u2009g<jats:sup>\u22121<\/jats:sup> at 50\u2005mA\u2009g<jats:sup>\u22121<\/jats:sup>), excellent rate capability (160.6\u2005mAh\u2009g<jats:sup>\u22121<\/jats:sup> at 1000\u2005mA\u2009g<jats:sup>\u22121<\/jats:sup>) and good cycling stability (165.5\u2005mAh\u2009g<jats:sup>\u22121<\/jats:sup> at 500\u2005mA\u2009g<jats:sup>\u22121<\/jats:sup> after 50\u2005cycles) with quasi\u2010solid\u2010state electrolyte. This work will provide insightful understanding of the materials design strategies to develop more efficient coordination polymer cathodes for LIBs.<\/jats:p>","DOI":"10.1002\/anie.202209458","type":"journal-article","created":{"date-parts":[[2022,7,28]],"date-time":"2022-07-28T10:31:13Z","timestamp":1659004273000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":33,"title":["A Monocrystalline Coordination Polymer with Multiple Redox Centers as a High\u2010Performance Cathode for Lithium\u2010Ion Batteries"],"prefix":"10.1002","volume":"61","author":[{"given":"Yuwen","family":"Luo","sequence":"first","affiliation":[{"name":"School of Chemistry and Chemical Engineering Guangdong Provincial Key Laboratory of Advanced Energy Storage Materials South China University of Technology  Guangzhou 510640 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