{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,4,5]],"date-time":"2026-04-05T13:52:29Z","timestamp":1775397149839,"version":"3.50.1"},"reference-count":44,"publisher":"Wiley","issue":"43","license":[{"start":{"date-parts":[[2022,8,30]],"date-time":"2022-08-30T00:00:00Z","timestamp":1661817600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/100010663","name":"H2020 European Research Council","doi-asserted-by":"publisher","award":["818862"],"award-info":[{"award-number":["818862"]}],"id":[{"id":"10.13039\/100010663","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2022,10,24]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>The preparation and structural characterization of [NEt<jats:sub>3<\/jats:sub>Me]<jats:sub>2<\/jats:sub>[SCl<jats:sub>6<\/jats:sub>] is described, which is the first example of a [SCl<jats:sub>6<\/jats:sub>]<jats:sup>2\u2212<\/jats:sup> dianion and of a halosulfate anion of the type [S<jats:sub><jats:italic>x<\/jats:italic><\/jats:sub>X<jats:sub><jats:italic>y<\/jats:italic><\/jats:sub>]<jats:sup><jats:italic>z<\/jats:italic>\u2212<\/jats:sup> in general. This dianion belongs to the group of 14\u2010valence electron AB<jats:sub>6<\/jats:sub>E systems and forms an octahedral structure in the solid\u2010state. Interestingly, co\u2010crystallization with CH<jats:sub>2<\/jats:sub>Cl<jats:sub>2<\/jats:sub> affords [NEt<jats:sub>3<\/jats:sub>Me]<jats:sub>2<\/jats:sub>[SCl<jats:sub>6<\/jats:sub>]\u22c54\u2009CH<jats:sub>2<\/jats:sub>Cl<jats:sub>2<\/jats:sub> containing [SCl<jats:sub>6<\/jats:sub>]<jats:sup>2\u2212<\/jats:sup> dianions with <jats:italic><jats:sc>C<\/jats:sc><\/jats:italic><jats:sub>4<jats:italic>v<\/jats:italic><\/jats:sub> symmetry. As suggested by quantum\u2010chemical calculations, the distortion of the structure is not caused by a stereochemically active lone pair but by enhanced hydrogen bonding interactions with CH<jats:sub>2<\/jats:sub>Cl<jats:sub>2<\/jats:sub>. At elevated temperatures, [NEt<jats:sub>3<\/jats:sub>Me]<jats:sub>2<\/jats:sub>[SCl<jats:sub>6<\/jats:sub>] decomposes to various sulfur chlorine compounds as shown by Raman spectroscopy. Cooling back to room temperature results in the selective formation of [NEt<jats:sub>3<\/jats:sub>Me]<jats:sub>2<\/jats:sub>[SCl<jats:sub>6<\/jats:sub>] which is comparable to the well\u2010studied SCl<jats:sub>4<\/jats:sub>.<\/jats:p>","DOI":"10.1002\/anie.202209684","type":"journal-article","created":{"date-parts":[[2022,8,4]],"date-time":"2022-08-04T12:44:28Z","timestamp":1659617068000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":7,"title":["Synthesis of a Hexachloro Sulfate(IV) Dianion Enabled by Polychloride Chemistry"],"prefix":"10.1002","volume":"61","author":[{"given":"Patrick","family":"Vo\u00dfnacker","sequence":"first","affiliation":[{"name":"Institut f\u00fcr Chemie und Biochemie\u2014Anorganische Chemie Freie Universit\u00e4t Berlin  Fabeckstra\u00dfe 34\/36 14195 Berlin Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Alisa","family":"W\u00fcst","sequence":"additional","affiliation":[{"name":"Institut f\u00fcr Chemie und Biochemie\u2014Anorganische Chemie Freie Universit\u00e4t Berlin  Fabeckstra\u00dfe 34\/36 14195 Berlin Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Carsten","family":"M\u00fcller","sequence":"additional","affiliation":[{"name":"Institut f\u00fcr Chemie und Biochemie\u2014Anorganische Chemie Freie Universit\u00e4t Berlin  Fabeckstra\u00dfe 34\/36 14195 Berlin Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Merlin","family":"Kleoff","sequence":"additional","affiliation":[{"name":"Institut f\u00fcr Chemie und Biochemie\u2014Anorganische Chemie Freie Universit\u00e4t Berlin  Fabeckstra\u00dfe 34\/36 14195 Berlin Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4552-5719","authenticated-orcid":false,"given":"Sebastian","family":"Riedel","sequence":"additional","affiliation":[{"name":"Institut f\u00fcr Chemie und Biochemie\u2014Anorganische Chemie Freie Universit\u00e4t Berlin  Fabeckstra\u00dfe 34\/36 14195 Berlin Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2022,8,30]]},"reference":[{"key":"e_1_2_3_1_1","unstructured":"\u00a0"},{"key":"e_1_2_3_2_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.6b00551"},{"key":"e_1_2_3_3_2","volume-title":"Ullmann's Encyclopedia of Industrial Chemistry (Chlorine)","author":"Schmittinger P.","year":"2011"},{"key":"e_1_2_3_4_1","doi-asserted-by":"publisher","DOI":"10.1021\/acssuschemeng.2c02186"},{"key":"e_1_2_3_5_1","doi-asserted-by":"publisher","DOI":"10.1126\/sciadv.abj5186"},{"key":"e_1_2_3_6_1","unstructured":"\u00a0"},{"key":"e_1_2_3_7_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202006268"},{"key":"e_1_2_3_7_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.202006268"},{"key":"e_1_2_3_8_2","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.202000847"},{"key":"e_1_2_3_9_2","doi-asserted-by":"publisher","DOI":"10.1002\/open.202000263"},{"key":"e_1_2_3_10_2","first-page":"13982","volume":"57","author":"Kotsyuda S.","year":"2020","journal-title":"Z. 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