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However, the efficient and straightforward access to such structures with diversity remains a formidable challenge. Herein, a general and practical protocol to aziridines and cyclopropanes synthesis using free XH\n                    <jats:sub>2<\/jats:sub>\n                    (X=C or N) with alkenes by thianthrenation is presented. This metal\u2010free protocol features the direct aziridination and cyclopropanation with unprotected XH\n                    <jats:sub>2<\/jats:sub>\n                    . Free sulfonamides, amides, carbamates, amines, and methylene with acidic protons, are good precursors, providing an attractive alternative for straightforward synthesis of aziridines and cyclopropanes from easily available starting materials.\n                  <\/jats:p>","DOI":"10.1002\/anie.202209929","type":"journal-article","created":{"date-parts":[[2022,8,17]],"date-time":"2022-08-17T12:19:08Z","timestamp":1660738748000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":91,"title":["Intermolecular Metal\u2010Free Cyclopropanation and Aziridination of Alkenes with XH\n                    <sub>2<\/sub>\n                    (X=N, C) by Thianthrenation**"],"prefix":"10.1002","volume":"61","author":[{"given":"Ming\u2010Shang","family":"Liu","sequence":"first","affiliation":[{"name":"Shenzhen Grubbs Institute and Department of Chemistry Southern University of Science and Technology Shenzhen 518055 Guangdong P.R. 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