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Such a transformation is relevant for industry, as shown by the synthesis of acetaldehyde from ethylene as well as for fine\u2010chemicals, because of the versatility of a carbonyl group placed at specific positions. In this regard, many contributions have focused on controlling the chemo\u2010 and regioselectivity of the olefin oxidation by means of well\u2010defined palladium catalysts under different sets of reaction conditions. However, the development of Wacker\u2010type processes that avoid the use of palladium catalysts has just emerged in the last few years, thereby paving the way for the generation of more sustainable procedures, including milder reaction conditions and green chemistry technologies. In this Minireview, we discuss the development of new catalytic processes that utilize more benign catalysts and sustainable reaction conditions.<\/jats:p>","DOI":"10.1002\/anie.202211016","type":"journal-article","created":{"date-parts":[[2022,9,27]],"date-time":"2022-09-27T05:43:49Z","timestamp":1664257429000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":50,"title":["Sustainable Wacker\u2010Type Oxidations"],"prefix":"10.1002","volume":"61","author":[{"given":"Purushothaman","family":"Rajeshwaran","sequence":"first","affiliation":[{"name":"Univ Rennes CNRS, ISCR\u2014UMR 6226  F-35000 Rennes France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jonathan","family":"Trouv\u00e9","sequence":"additional","affiliation":[{"name":"Univ Rennes CNRS, ISCR\u2014UMR 6226  F-35000 Rennes France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Khalil","family":"Youssef","sequence":"additional","affiliation":[{"name":"Univ Rennes CNRS, ISCR\u2014UMR 6226  F-35000 Rennes France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0961-4530","authenticated-orcid":false,"given":"Rafael","family":"Gramage\u2010Doria","sequence":"additional","affiliation":[{"name":"Univ Rennes CNRS, ISCR\u2014UMR 6226  F-35000 Rennes France"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2022,10,26]]},"reference":[{"key":"e_1_2_8_1_1","unstructured":"\u00a0"},{"key":"e_1_2_8_2_2","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.143"},{"key":"e_1_2_8_3_2","doi-asserted-by":"publisher","DOI":"10.1039\/B918763B"},{"key":"e_1_2_8_4_2","doi-asserted-by":"publisher","DOI":"10.1002\/cssc.200900118"},{"key":"e_1_2_8_5_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200800012"},{"key":"e_1_2_8_5_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200800012"},{"key":"e_1_2_8_6_2","doi-asserted-by":"publisher","DOI":"10.1002\/cben.201400034"},{"key":"e_1_2_8_7_1","unstructured":"\u00a0"},{"key":"e_1_2_8_8_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr050523v"},{"key":"e_1_2_8_9_2","volume-title":"Oxidation of Alochols to Aldehydes and Ketones","author":"Tojo G.","year":"2006"},{"key":"e_1_2_8_10_2","doi-asserted-by":"publisher","DOI":"10.1002\/9781119304197"},{"key":"e_1_2_8_11_2","doi-asserted-by":"publisher","DOI":"10.1002\/9783527632039"},{"key":"e_1_2_8_12_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.0c00774"},{"key":"e_1_2_8_13_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.5b00122"},{"key":"e_1_2_8_14_2","doi-asserted-by":"crossref","first-page":"465","DOI":"10.1002\/9783527651733.ch7","volume-title":"Applied Homogeneous Catalysis with Organometallic Compounds: A Comprehensive Handbook in Four Volumes","author":"Teles J. 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