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A collection of carbonaceous materials with different pore networks and high nitrogen content was characterized and used to catalyze four reactions to deduce structure\u2013activity relationships. The CO\n                    <jats:sub>2<\/jats:sub>\n                    cycloaddition and Knoevenagel reaction depend on Lewis basic sites (electron\u2010rich nitrogen species). The absence of large conjugated carbon domains resulting from the introduction of large amounts of nitrogen in the carbon network is responsible for poor redox activity, as observed through the catalytic reduction of nitrobenzene with hydrazine and the catalytic oxidation of 3,3\u2032,5,5\u2032\u2010tetramethylbenzidine using hydroperoxide. The material with the highest activity towards Lewis acid catalysis (in the hydrolysis of (dimethoxymethyl)benzene to benzaldehyde) is the most effective for small molecule activation and presents the highest concentration of electron\u2010poor nitrogen species.\n                  <\/jats:p>","DOI":"10.1002\/anie.202211663","type":"journal-article","created":{"date-parts":[[2022,10,28]],"date-time":"2022-10-28T02:08:17Z","timestamp":1666922897000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":28,"title":["Catalytic Properties of High Nitrogen Content Carbonaceous Materials"],"prefix":"10.1002","volume":"62","author":[{"given":"Enrico","family":"Lepre","sequence":"first","affiliation":[{"name":"Department of Colloid Chemistry Max Planck Institute of Colloids and Interfaces, Potsdam Science Park  Am M\u00fchlenberg 1 14476 Potsdam 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