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Herein, we report a facile chemical vapor deposition strategy to synthesize single\u2010Ni atoms decorated hollow S\/N\u2010doped football\u2010like carbon spheres (Ni SAs@S\/N\u2010FCS). Specifically, the CdS@3\u2010aminophenol\/formaldehyde is carbonized into S\/N\u2010FCS. The gas\u2010migrated Ni species are anchored on the surface of S\/N\u2010FCS simultaneously, yielding Ni SAs@S\/N\u2010FCS. The obtained catalyst exhibits outstanding performance for alkaline oxygen evolution reaction (OER) with an overpotential of 249\u2005mV at 10\u2005mA\u2009cm<jats:sup>\u22122<\/jats:sup>, a small Tafel slope of 56.5\u2005mV\u2009dec<jats:sup>\u22121<\/jats:sup>, and ultra\u2010long stability up to 166\u2005hours without obvious fading. Moreover, the potential\u2010driven dynamic behaviors of Ni\u2010N<jats:sub>4<\/jats:sub> sites and the contribution of the S dopant at different locations in the matrix to the OER activity are revealed by the operando X\u2010ray absorption spectroscopy and theoretical calculations, respectively.<\/jats:p>","DOI":"10.1002\/anie.202212542","type":"journal-article","created":{"date-parts":[[2022,9,12]],"date-time":"2022-09-12T09:49:38Z","timestamp":1662976178000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":99,"title":["Surface\u2010Exposed Single\u2010Ni Atoms with Potential\u2010Driven Dynamic Behaviors for Highly Efficient Electrocatalytic Oxygen Evolution"],"prefix":"10.1002","volume":"61","author":[{"given":"Yafei","family":"Zhao","sequence":"first","affiliation":[{"name":"School of Chemical and Biomedical Engineering Nanyang Technological University  62 Nanyang Drive Singapore 637459 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