{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,12]],"date-time":"2026-10-12T22:14:29Z","timestamp":1791843269662,"version":"4.3.4"},"reference-count":47,"publisher":"Wiley","issue":"2","license":[{"start":{"date-parts":[[2022,12,7]],"date-time":"2022-12-07T00:00:00Z","timestamp":1670371200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/100010663","name":"H2020 European Research Council","doi-asserted-by":"publisher","award":["677367"],"award-info":[{"award-number":["677367"]}],"id":[{"id":"10.13039\/100010663","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100010434","name":"\u201cla Caixa\u201d Foundation","doi-asserted-by":"publisher","award":["LCF\/BQ\/EU19\/11710077"],"award-info":[{"award-number":["LCF\/BQ\/EU19\/11710077"]}],"id":[{"id":"10.13039\/100010434","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2023,1,9]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Reaction of a hexagonal planar palladium complex featuring a [PdMg\n                    <jats:sub>3<\/jats:sub>\n                    H\n                    <jats:sub>3<\/jats:sub>\n                    ] core with H\n                    <jats:sub>2<\/jats:sub>\n                    is reversible and leads to the formation of a new [PdMg\n                    <jats:sub>2<\/jats:sub>\n                    H\n                    <jats:sub>4<\/jats:sub>\n                    ] tetrahydride species alongside an equivalent of a magnesium hydride co\u2010product [MgH]. While the reversibility of this process prevented isolation of [PdMg\n                    <jats:sub>2<\/jats:sub>\n                    H\n                    <jats:sub>4<\/jats:sub>\n                    ], analogous [PtMg\n                    <jats:sub>2<\/jats:sub>\n                    H\n                    <jats:sub>4<\/jats:sub>\n                    ] and [PtZn\n                    <jats:sub>2<\/jats:sub>\n                    H\n                    <jats:sub>4<\/jats:sub>\n                    ] complexes could be isolated and characterised through independent syntheses. Computational analysis (DFT, AIM, NCIPlot) of the bonding in a series of heterometallic tetrahydride compounds (Ni\u2013Pt; Mg and Zn) suggests that these complexes are best described as square planar with marginal metal\u2010metal interactions; the strength of which increases slightly as group 10 is descended and increases from Mg to Zn. DFT calculations support a mechanism for H\n                    <jats:sub>2<\/jats:sub>\n                    activation involving a ligand\u2010assisted oxidative addition to Pd. These findings were exploited to develop a catalytic protocol for H\/D exchange into magnesium hydride and zinc hydride bonds.\n                  <\/jats:p>","DOI":"10.1002\/anie.202213001","type":"journal-article","created":{"date-parts":[[2022,11,9]],"date-time":"2022-11-09T11:29:52Z","timestamp":1667993392000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":9,"title":["Reversible Dihydrogen Activation and Catalytic H\/D Exchange with Group 10 Heterometallic Complexes**"],"prefix":"10.1002","volume":"62","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-3214-0150","authenticated-orcid":false,"given":"Mart\u00ed","family":"Gar\u00e7on","sequence":"first","affiliation":[{"name":"Department of Chemistry Imperial College London Molecular Sciences Research Hub 82 Wood Lane London W12 0BZ UK"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Andreas","family":"Phanopoulos","sequence":"additional","affiliation":[{"name":"Department of Chemistry Imperial College London Molecular Sciences Research Hub 82 Wood Lane London W12 0BZ UK"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Andrew J. P.","family":"White","sequence":"additional","affiliation":[{"name":"Department of Chemistry Imperial College London Molecular Sciences Research Hub 82 Wood Lane London W12 0BZ UK"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9339-9182","authenticated-orcid":false,"given":"Mark R.","family":"Crimmin","sequence":"additional","affiliation":[{"name":"Department of Chemistry Imperial College London Molecular Sciences Research Hub 82 Wood Lane London W12 0BZ UK"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2022,12,7]]},"reference":[{"key":"e_1_2_3_1_1","doi-asserted-by":"publisher","DOI":"10.1039\/C0CC02245D"},{"key":"e_1_2_3_2_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja211419t"},{"key":"e_1_2_3_3_1","doi-asserted-by":"publisher","DOI":"10.1021\/ic301733r"},{"key":"e_1_2_3_4_1","doi-asserted-by":"publisher","DOI":"10.1021\/om400281v"},{"key":"e_1_2_3_5_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja408397v"},{"key":"e_1_2_3_6_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201308175"},{"key":"e_1_2_3_6_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201308175"},{"key":"e_1_2_3_7_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja505843g"},{"key":"e_1_2_3_8_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201410781"},{"key":"e_1_2_3_8_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201410781"},{"key":"e_1_2_3_9_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201410828"},{"key":"e_1_2_3_9_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201410828"},{"key":"e_1_2_3_10_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6b01320"},{"key":"e_1_2_3_11_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b02870"},{"key":"e_1_2_3_12_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9SC02018G"},{"key":"e_1_2_3_13_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6b05243"},{"key":"e_1_2_3_14_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c01062"},{"key":"e_1_2_3_15_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.organomet.1c00088"},{"key":"e_1_2_3_16_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.6b00048"},{"key":"e_1_2_3_17_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1CS01171E"},{"key":"e_1_2_3_18_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.5b02395"},{"key":"e_1_2_3_19_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja805164n"},{"key":"e_1_2_3_20_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202208855"},{"key":"e_1_2_3_20_2","doi-asserted-by":"crossref","DOI":"10.1002\/ange.202208855","volume":"134","year":"2022","journal-title":"Angew. Chem."},{"key":"e_1_2_3_21_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.2c07402"},{"key":"e_1_2_3_22_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41586-019-1616-2"},{"key":"e_1_2_3_23_1","unstructured":"Pt-Mg\u22c5TMEDAis not the only product of this reaction and we have previously reported the Pt analogue of1as a minor product from the reaction of [Pt(Me)2(k2-TMEDA)] with[2]2. These compounds are present in an approximate 2\u2009:\u20091 ratio in the crude reaction mixture."},{"key":"e_1_2_3_24_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202014960"},{"key":"e_1_2_3_24_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.202014960"},{"key":"e_1_2_3_25_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8CC06392C"},{"key":"e_1_2_3_26_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja00221a005"},{"key":"e_1_2_3_27_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja00011a019"},{"key":"e_1_2_3_28_1","unstructured":"Deposition Numbers2107424 (forPt-Mg\u22c5TMEDA) and 2107425 (forPt-Zn)contain the supplementary crystallographic data for this paper. These data are provided free of charge by the joint Cambridge Crystallographic Data Centre and Fachinformationszentrum KarlsruheAccess Structures service."},{"key":"e_1_2_3_29_1","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.201300317"},{"key":"e_1_2_3_30_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja994089o"},{"key":"e_1_2_3_31_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.199107591"},{"key":"e_1_2_3_31_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.19911030707"},{"key":"e_1_2_3_32_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja106266v"},{"key":"e_1_2_3_33_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.8b00155"},{"key":"e_1_2_3_34_1","unstructured":"Structures were optimised in the gas-phase with the \u03c9B97X functional and a hybrid basis-set 6\u201331G*(C H)\/6-311+G* (N)\/6-31++G(d 3pd) (hydrides)\/SDDAll (metals). Single point corrections on optimised stationary points were carried out using the \u03c9B97X functional and def2-TZVPP (Mg Zn C N H)\/SDD (Ni Pd Pt) basis-set using the PCM (benzene) solvation model."},{"key":"e_1_2_3_35_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202211948"},{"key":"e_1_2_3_35_2","doi-asserted-by":"crossref","DOI":"10.1002\/ange.202211948","volume":"134","year":"2022","journal-title":"Angew. Chem."},{"key":"e_1_2_3_36_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200603224"},{"key":"e_1_2_3_36_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200603224"},{"key":"e_1_2_3_37_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202111462"},{"key":"e_1_2_3_37_2","doi-asserted-by":"crossref","DOI":"10.1002\/ange.202111462","volume":"134","year":"2022","journal-title":"Angew. Chem. Int. 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