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The mildness of the method enables access to high surface areas by avoiding structural changes in the framework that often plague thermal activation methods. A distinction from previous methods is that DME activation succeeds for materials with coordinatively unsaturated sites (CUS) and non\u2010CUS MOFs as well. DME displaces solvent molecules occupying the pores of the MOF as well as those coordinated to metal centers; reducing evacuation temperature by using a coordinating, yet highly volatile guest enables low temperature activation with structural retention as demonstrated surface area measurements that match or exceed existing activation protocols.<\/jats:p>","DOI":"10.1002\/anie.202213190","type":"journal-article","created":{"date-parts":[[2022,11,2]],"date-time":"2022-11-02T14:19:21Z","timestamp":1667398761000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":23,"title":["Superior Metal\u2010Organic Framework Activation with Dimethyl Ether"],"prefix":"10.1002","volume":"61","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-2449-7985","authenticated-orcid":false,"given":"Keenan R.","family":"Wright","sequence":"first","affiliation":[{"name":"Department of Chemistry Institution University of Michigan  930 North University Avenue Ann Arbor MI 48109-1055 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4857-8795","authenticated-orcid":false,"given":"Karabi","family":"Nath","sequence":"additional","affiliation":[{"name":"Department of Chemistry Institution University of Michigan  930 North University Avenue Ann Arbor MI 48109-1055 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4926-2752","authenticated-orcid":false,"given":"Adam J.","family":"Matzger","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Macromolecular Science and Engineering Program University of Michigan  930 North University Avenue Ann Arbor MI 48109-1055 USA"},{"name":"Department of Chemistry Institution University of Michigan  930 North University Avenue Ann Arbor MI 48109-1055 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2022,11,23]]},"reference":[{"key":"e_1_2_3_1_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201709187"},{"key":"e_1_2_3_1_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201709187"},{"key":"e_1_2_3_2_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemmater.6b02626"},{"key":"e_1_2_3_3_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemmater.8b03378"},{"key":"e_1_2_3_4_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.0c00722"},{"key":"e_1_2_3_5_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200462786"},{"key":"e_1_2_3_5_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200462786"},{"key":"e_1_2_3_6_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja800669j"},{"key":"e_1_2_3_7_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.9b00223"},{"key":"e_1_2_3_8_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja981669x"},{"key":"e_1_2_3_9_1","doi-asserted-by":"publisher","DOI":"10.1021\/ar1000617"},{"key":"e_1_2_3_10_1","doi-asserted-by":"publisher","DOI":"10.1039\/c3ce41232f"},{"key":"e_1_2_3_11_1","doi-asserted-by":"publisher","DOI":"10.1039\/C4CC02401J"},{"key":"e_1_2_3_12_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.9b02764"},{"key":"e_1_2_3_13_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsmaterialslett.9b00240"},{"key":"e_1_2_3_14_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja808853q"},{"key":"e_1_2_3_15_1","doi-asserted-by":"publisher","DOI":"10.1039\/c2cc37793d"},{"key":"e_1_2_3_16_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja01853a068"},{"key":"e_1_2_3_17_1","doi-asserted-by":"publisher","DOI":"10.1021\/je0340046"},{"key":"e_1_2_3_18_1","doi-asserted-by":"publisher","DOI":"10.1021\/je800375t"},{"key":"e_1_2_3_19_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jced.8b00037"},{"key":"e_1_2_3_20_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.1083440"},{"key":"e_1_2_3_21_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.langmuir.6b02802"},{"key":"e_1_2_3_22_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201101383"},{"key":"e_1_2_3_23_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.283.5405.1148"},{"key":"e_1_2_3_24_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-019-08483-9"},{"key":"e_1_2_3_25_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201702668"},{"key":"e_1_2_3_26_1","first-page":"3674","volume":"6","author":"Hendon C.","year":"2015","journal-title":"R. 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