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To address this, we developed a worthwhile avenue for creating new noncentrosymmetric chiral Ln<jats:sup>3+<\/jats:sup> materials Ln<jats:sub>2<\/jats:sub>(SeO<jats:sub>3<\/jats:sub>)<jats:sub>2<\/jats:sub>(SO<jats:sub>4<\/jats:sub>)(H<jats:sub>2<\/jats:sub>O)<jats:sub>2<\/jats:sub> (Ln=Sm, Dy, Yb) by mixed\u2010ligand design. The materials exhibit phase\u2010matching nonlinear optical responses, elucidating the feasibility of the heteroanionic strategy. Ln<jats:sub>2<\/jats:sub>(SeO<jats:sub>3<\/jats:sub>)<jats:sub>2<\/jats:sub>(SO<jats:sub>4<\/jats:sub>)(H<jats:sub>2<\/jats:sub>O)<jats:sub>2<\/jats:sub> displays paramagnetic property with strong magnetic anisotropy facilitated by large spin\u2010orbit coupling. This study demonstrates a new chemical pathway for creating previously unknown polar chiral magnets with multiple functionalities.<\/jats:p>","DOI":"10.1002\/anie.202213499","type":"journal-article","created":{"date-parts":[[2022,10,4]],"date-time":"2022-10-04T18:33:46Z","timestamp":1664908426000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":34,"title":["Ln<sub>2<\/sub>(SeO<sub>3<\/sub>)<sub>2<\/sub>(SO<sub>4<\/sub>)(H<sub>2<\/sub>O)<sub>2<\/sub> (Ln=Sm, Dy, Yb): A Mixed\u2010Ligand Pathway to New Lanthanide(III) Multifunctional Materials Featuring Nonlinear Optical and Magnetic Anisotropy Properties"],"prefix":"10.1002","volume":"61","author":[{"given":"Ebube E.","family":"Oyeka","sequence":"first","affiliation":[{"name":"Department of Chemistry Clemson University  Clemson SC 29630 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Micha\u0142 J.","family":"Winiarski","sequence":"additional","affiliation":[{"name":"Faculty of Applied Physics and Mathematics and Advanced Materials Center Gdansk University of Technology  ul Narutowicza 11\/12 80-233 Gdansk Poland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hanna","family":"\u015awi\u0105tek","sequence":"additional","affiliation":[{"name":"Faculty of Applied Physics and Mathematics and Advanced Materials Center Gdansk University of Technology  ul Narutowicza 11\/12 80-233 Gdansk Poland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wyatt","family":"Balliew","sequence":"additional","affiliation":[{"name":"Department of Chemistry Clemson University  Clemson SC 29630 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Colin D.","family":"McMillen","sequence":"additional","affiliation":[{"name":"Department of Chemistry Clemson University  Clemson SC 29630 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mingli","family":"Liang","sequence":"additional","affiliation":[{"name":"Department of Chemistry University of Houston  Houston TX 77204 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"suffix":"II","given":"Maurice","family":"Sorolla","sequence":"additional","affiliation":[{"name":"Department of Chemical Engineering University of the Philippines Diliman  Quezon City 1101 Philippines"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2395-3555","authenticated-orcid":false,"given":"Thao T.","family":"Tran","sequence":"additional","affiliation":[{"name":"Department of Chemistry Clemson University  Clemson SC 29630 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2022,10,25]]},"reference":[{"key":"e_1_2_7_1_1","unstructured":"\u00a0"},{"key":"e_1_2_7_2_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.1c02004"},{"key":"e_1_2_7_3_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b08559"},{"key":"e_1_2_7_4_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202003399"},{"key":"e_1_2_7_4_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.202003399"},{"key":"e_1_2_7_5_2","doi-asserted-by":"publisher","DOI":"10.1038\/srep24046"},{"key":"e_1_2_7_6_2","first-page":"09E","volume":"107","author":"Kim J. 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