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A novel MOF, using low toxic aluminum (Al) as the metal, named as ZJU\u2010620(Al), with uniform micropore size of 8.37\u00b10.73\u2005\u00c5 and specific surface area of 1347\u2005m<jats:sup>2<\/jats:sup>\u2009g<jats:sup>\u22121<\/jats:sup>, was synthesized. It is constructed by one\u2010dimensional rod\u2010shaped AlO<jats:sub>6<\/jats:sub> clusters, formate ligands and 4,4\u2032,4\u2032\u2032\u2010(2,4,6\u2010trimethylbenzene\u20101,3,5\u2010triyl) tribenzoic ligands. ZJU\u2010620(Al) exhibits excellent chemical\u2010thermal stability and adsorption for trace BTEX, <jats:italic>e.g<\/jats:italic>., benzene adsorption of 3.80\u2005mmol\u2009g<jats:sup>\u22121<\/jats:sup> at <jats:italic>P<\/jats:italic>\/<jats:italic>P<\/jats:italic><jats:sub>0<\/jats:sub>=0.01 and 298\u2005K, which is the largest one reported. Using Grand Canonical Monte Carlo simulations and Single\u2010crystal X\u2010ray diffraction analyses, it was observed that the excellent adsorption could be attributed to the high affinity of BTEX molecules in ZJU\u2010620(Al) micropores because the kinetic diameters of BTEX are close up to the pore size of ZJU\u2010620(Al).<\/jats:p>","DOI":"10.1002\/anie.202215296","type":"journal-article","created":{"date-parts":[[2023,1,26]],"date-time":"2023-01-26T06:10:47Z","timestamp":1674713447000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":47,"title":["A Novel Aluminum\u2010Based Metal\u2010Organic Framework with Uniform Micropores for Trace BTEX Adsorption"],"prefix":"10.1002","volume":"62","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-1910-8110","authenticated-orcid":false,"given":"Laigang","family":"Hu","sequence":"first","affiliation":[{"name":"Department of Environmental Science Zhejiang University  310058 Hangzhou 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