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However, currently commercialized supercapacitors still suffer limited energy densities. Here we report an unprecedentedly respiring supercapacitor with chlorine gas iteratively re\u2010inspires in porous carbon materials, that improves the energy density by orders of magnitude. Both electrochemical results and theoretical calculations show that porous carbon with pore size around 3\u2005nm delivers the best chlorine evolution and adsorption performance. The respiring supercapacitor with multi\u2010wall carbon nanotube as the cathode and NaTi<jats:sub>2<\/jats:sub>(PO<jats:sub>4<\/jats:sub>)<jats:sub>3<\/jats:sub> as the anode can store specific energy of 33\u2005Wh\u2009kg<jats:sup>\u22121<\/jats:sup> with negligible capacity loss over 30\u2009000 cycles. The energy density can be further improved to 53\u2005Wh\u2009kg<jats:sup>\u22121<\/jats:sup> by replacing NaTi<jats:sub>2<\/jats:sub>(PO<jats:sub>4<\/jats:sub>)<jats:sub>3<\/jats:sub> with zinc anode. Furthermore, thanks to the extraordinary reaction kinetics of chlorine gas, this respiring supercapacitor performs an extremely high\u2010power density of 50\u2009000\u2005W\u2009kg<jats:sup>\u22121<\/jats:sup>.<\/jats:p>","DOI":"10.1002\/anie.202215342","type":"journal-article","created":{"date-parts":[[2022,11,21]],"date-time":"2022-11-21T03:16:19Z","timestamp":1669000579000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":29,"title":["High Power\u2010 and Energy\u2010Density Supercapacitors through the Chlorine Respiration Mechanism"],"prefix":"10.1002","volume":"62","author":[{"given":"Xiaotong","family":"Fan","sequence":"first","affiliation":[{"name":"Key Laboratory for Ultrafine Materials of Ministry of Education Shanghai Engineering Research Center of Hierarchical Nanomaterials Frontiers Science Center for Materiobiology and Dynamic Chemistry School of Chemical Engineering School of Materials Science and Engineering East China University of Science &amp; 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