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It was found that a benzene\u20101,3,5\u2010tricarboxamide (BTA) motif with an aminopyridine group in each arm could coordinate with Ag\n                    <jats:sup>I<\/jats:sup>\n                    and self\u2010assemble into nanospheres. Upon sonication, symmetry breaking occurred and the nanospheres transferred into helical nanofibers with strong CD signals. Although the sign of the CD signals appeared randomly, it could be controlled by using the as\u2010made chiral assemblies as a seed. Furthermore, it was found that the charge transport of the helical nanofibers was highly selective with a spin\u2010polarization transport of up to 45\u2009%, although the chiral nanofibers are composed exclusively from achiral building blocks. This work demonstrates symmetry breaking under sonication and the chiral\u2010selective spin\u2010filtering effect.\n                  <\/jats:p>","DOI":"10.1002\/anie.202215867","type":"journal-article","created":{"date-parts":[[2022,12,15]],"date-time":"2022-12-15T23:03:20Z","timestamp":1671145400000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":41,"title":["Ultrasound\u2010Directed Symmetry Breaking and Spin Filtering of Supramolecular Assemblies from only Achiral Building Blocks"],"prefix":"10.1002","volume":"62","author":[{"given":"Yutao","family":"Sang","sequence":"first","affiliation":[{"name":"Beijing National Laboratory for Molecular Sciences CAS Key Laboratory of Colloid Interface and Chemical Thermodynamics CAS Research\/Education Center for Excellence in Molecular Sciences Department Institute of Chemistry Chinese Academy of Sciences  Beijing 100190 P. R. 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