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However, the performance of electrolytes is often negatively influenced by high solute concentration. Herein, we designed a high\u2010potential (0.5\u2005V vs. Ag\/Ag\n                    <jats:sup>+<\/jats:sup>\n                    ) catholyte for RFBs, where the charged and discharged species are both gaseous nitrogen oxides (NO\n                    <jats:sub>\n                      <jats:italic>x<\/jats:italic>\n                    <\/jats:sub>\n                    ). These species can be liberated from the liquid electrolyte and stored in a separate gas container, allowing scale\u2010up of storage capacity without increasing the concentration and volume of the electrolyte. The oxidation of NO in the presence of NO\n                    <jats:sub>3<\/jats:sub>\n                    <jats:sup>\u2212<\/jats:sup>\n                    affords N\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>3<\/jats:sub>\n                    , and the reduction of N\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>3<\/jats:sub>\n                    regenerates NO and NO\n                    <jats:sub>3<\/jats:sub>\n                    <jats:sup>\u2212<\/jats:sup>\n                    , together affording the electrochemical reaction: NO\n                    <jats:sub>3<\/jats:sub>\n                    <jats:sup>\u2212<\/jats:sup>\n                    +3\u2009NO\u21cc2\u2009N\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>3<\/jats:sub>\n                    +e\n                    <jats:sup>\u2212<\/jats:sup>\n                    with a low mass\/charge ratio of 152\u2005grams per mole of stored electron. A proof\u2010of\u2010concept NO\n                    <jats:sub>\n                      <jats:italic>x<\/jats:italic>\n                    <\/jats:sub>\n                    symmetric H\u2010cell shows 200 stable cycles over 400\u2005hours with &gt;97\u2009% Coulombic efficiency and negligible capacity decay.\n                  <\/jats:p>","DOI":"10.1002\/anie.202216889","type":"journal-article","created":{"date-parts":[[2023,1,2]],"date-time":"2023-01-02T09:54:07Z","timestamp":1672653247000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":7,"title":["Gaseous Nitrogen Oxides Catholyte for Rechargeable Redox Flow Batteries"],"prefix":"10.1002","volume":"62","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-4767-0530","authenticated-orcid":false,"given":"Weiyao","family":"Zhang","sequence":"first","affiliation":[{"name":"Department of Chemistry &amp; Biochemistry The Ohio State University  100 West 18th Avenue Columbus OH-43210 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xin","family":"Yang","sequence":"additional","affiliation":[{"name":"Department of Chemistry &amp; Biochemistry The Ohio State University  100 West 18th Avenue Columbus OH-43210 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2536-4324","authenticated-orcid":false,"given":"Shiyu","family":"Zhang","sequence":"additional","affiliation":[{"name":"Department of Chemistry &amp; Biochemistry The Ohio State University  100 West 18th Avenue Columbus OH-43210 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2023,1,19]]},"reference":[{"key":"e_1_2_7_1_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr500720t"},{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201604925"},{"key":"e_1_2_7_2_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201604925"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsenergylett.7b00361"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1039\/C6EE02027E"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jpowsour.2017.05.057"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1039\/C6EE02057G"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201505000"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1038\/nature15746"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201203119"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1002\/open.201600155"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202103478"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.aab3033"},{"key":"e_1_2_7_13_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201907934"},{"key":"e_1_2_7_13_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201907934"},{"key":"e_1_2_7_14_1","doi-asserted-by":"publisher","DOI":"10.3390\/molecules26133823"},{"key":"e_1_2_7_15_1","first-page":"7","volume":"524","author":"Wang C.","year":"2022","journal-title":"J. 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