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Recently, nucleophilic low\u2010valent Al\n                    <jats:sup>I<\/jats:sup>\n                    aluminyl anions have showcased oxidative additions towards arenes C\u2212C and\/or C\u2212H bonds. Herein, we communicate compelling evidence of an Al\n                    <jats:sup>II<\/jats:sup>\n                    radical addition reaction to the benzene ring. The electron reduction of a ligand stabilized precursor with KC\n                    <jats:sub>8<\/jats:sub>\n                    in benzene furnishes a double addition to the benzene ring instead of a C\u2212H bond activation, producing the corresponding cyclohexa\u20101,3(orl,4)\u2010dienes as Birch\u2010type reduction product. X\u2010ray crystallographic analysis, EPR spectroscopy, and DFT results suggest this reactivity proceeds through a stable Al\n                    <jats:sup>II<\/jats:sup>\n                    radical intermediate, whose stability is a consequence of a rigid scaffold in combination with strong steric protection.\n                  <\/jats:p>","DOI":"10.1002\/anie.202217184","type":"journal-article","created":{"date-parts":[[2023,1,3]],"date-time":"2023-01-03T06:58:59Z","timestamp":1672729139000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":24,"title":["Evidence of Al\n                    <sup>II<\/sup>\n                    Radical Addition to Benzene"],"prefix":"10.1002","volume":"62","author":[{"given":"Debdeep","family":"Mandal","sequence":"first","affiliation":[{"name":"General and Inorganic Chemistry Department University of Saarland Campus C4.1 66123 Saarbr\u00fccken Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"T. 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