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Besides offering expedient access to seldom studied boryl metal carbenes, these BMIDA gold carbene species undergo facile insertions into methyl, methylene, methine, and benzylic C\u2212H bonds in the absence of the Thorpe\u2013Ingold effect. They also undergo efficient OH insertion, cyclopropanation, and F\u2212C alkylations. This chemistry provides rapid access to structurally diverse \u03b1\u2010BMIDA ketones, which are scarcely documented. 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