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Herein we explore the behavior of 1,3\u2010disubstituted BCP moieties on metal surfaces by combining low\u2010temperature scanning tunneling microscopy \/ non\u2010contact atomic force microscopy studies with density functional theory modeling. We examine the configuration of individual BCP\u2010containing precursors on Au(111), their supramolecular assembly and thermally activated dehalogenative coupling reactions, affording polymeric chains with incorporated electronically isolating units. Our studies not only provide the first sub\u2010molecular insights of the BCP scaffold behavior on surfaces, but also extend the potential application of BCP derivatives towards integration in custom\u2010designed surface architectures.<\/jats:p>","DOI":"10.1002\/anie.202218211","type":"journal-article","created":{"date-parts":[[2023,3,1]],"date-time":"2023-03-01T18:58:50Z","timestamp":1677697130000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":8,"title":["On\u2010Surface Synthesis of Polyphenylene Wires Comprising Rigid Aliphatic Bicyclo[1.1.1]Pentane Isolator Units"],"prefix":"10.1002","volume":"62","author":[{"given":"Biao","family":"Yang","sequence":"first","affiliation":[{"name":"Institute for Advanced Study (TUM-IAS) Focus Group\u2014Molecular and Interfacial Engineering of Organic Nanosystems Technical University of Munich  Lichtenberg Str. 2a 85748 Garching Germany"},{"name":"Physics Department E20 Technical 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