{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,15]],"date-time":"2026-10-15T21:53:53Z","timestamp":1792101233581,"version":"4.4.0"},"reference-count":71,"publisher":"Wiley","issue":"12","license":[{"start":{"date-parts":[[2023,2,8]],"date-time":"2023-02-08T00:00:00Z","timestamp":1675814400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["21902157"],"award-info":[{"award-number":["21902157"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["51721002"],"award-info":[{"award-number":["51721002"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22279139"],"award-info":[{"award-number":["22279139"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2023,3,13]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Designing polymeric photocatalysts at the molecular level to modulate the photogenerated charge behavior is a promising and challenging strategy for efficient hydrogen peroxide (H<jats:sub>2<\/jats:sub>O<jats:sub>2<\/jats:sub>) photosynthesis. Here, we introduce electron\u2010deficient 1,4\u2010dihydroxyanthraquinone (DHAQ) into the framework of resorcinol\u2010formaldehyde (RF) resin, which modulates the donor\/acceptor ratio from the perspective of molecular design for promoting the charge separation. Interestingly, H<jats:sub>2<\/jats:sub>O<jats:sub>2<\/jats:sub> can be produced via oxygen reduction and water oxidation pathways, verified by isotopic labeling and in situ characterization techniques. Density functional theory (DFT) calculations elucidate that DHAQ can reduce the energy barrier for H<jats:sub>2<\/jats:sub>O<jats:sub>2<\/jats:sub> production. RF\u2010DHAQ exhibits excellent overall photosynthesis of H<jats:sub>2<\/jats:sub>O<jats:sub>2<\/jats:sub> with a solar\u2010to\u2010chemical conversion (SCC) efficiency exceeding 1.2\u2009%. This work opens a new avenue to design polymeric photocatalysts at the molecular level for high\u2010efficiency artificial photosynthesis.<\/jats:p>","DOI":"10.1002\/anie.202218318","type":"journal-article","created":{"date-parts":[[2022,12,29]],"date-time":"2022-12-29T05:39:13Z","timestamp":1672292353000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":161,"title":["Molecular Level Modulation of Anthraquinone\u2010containing Resorcinol\u2010formaldehyde Resin Photocatalysts for H<sub>2<\/sub>O<sub>2<\/sub> Production with Exceeding 1.2\u2009% Efficiency"],"prefix":"10.1002","volume":"62","author":[{"given":"Chen","family":"Zhao","sequence":"first","affiliation":[{"name":"State Key Laboratory of Catalysis Dalian Institute of Chemical Physics Chinese Academy of Sciences  457 Zhongshan Road Dalian 116023 China"},{"name":"Center of Materials Science and Optoelectronics Engineering University of Chinese Academy of Sciences  Beijing 100049 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xinyao","family":"Wang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Catalysis Dalian Institute of Chemical Physics Chinese Academy of Sciences  457 Zhongshan Road Dalian 116023 China"},{"name":"Center of Materials Science and Optoelectronics Engineering University of Chinese Academy of Sciences  Beijing 100049 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yanfeng","family":"Yin","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Molecular Reaction Dynamics and the Dynamic Research Center for Energy and Environmental Materials Dalian Institute of Chemical Physics Chinese Academy of Sciences  Dalian 116023 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wenming","family":"Tian","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Molecular Reaction Dynamics and the Dynamic Research Center for Energy and Environmental Materials Dalian Institute of Chemical Physics Chinese Academy of Sciences  Dalian 116023 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Guang","family":"Zeng","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Catalysis Dalian Institute of Chemical Physics Chinese Academy of Sciences  457 Zhongshan Road Dalian 116023 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Haitao","family":"Li","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Catalysis Dalian Institute of Chemical Physics Chinese Academy of Sciences  457 Zhongshan Road Dalian 116023 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sheng","family":"Ye","sequence":"additional","affiliation":[{"name":"College of Science &amp; School of Plant Protection Anhui Agricultural University  Hefei 230036 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Limin","family":"Wu","sequence":"additional","affiliation":[{"name":"Department of Materials Science and State Key Laboratory of Molecular Engineering of Polymers Fudan University  200433 Shanghai China"},{"name":"Inner Mongolia University  Hohhot, Inner Mongolia 010021 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5114-0404","authenticated-orcid":false,"given":"Jian","family":"Liu","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Catalysis Dalian Institute of Chemical Physics Chinese Academy of Sciences  457 Zhongshan Road Dalian 116023 China"},{"name":"Inner Mongolia University  Hohhot, Inner Mongolia 010021 P. R. China"},{"name":"DICP-Surrey Joint Centre for Future Materials Department of Chemical and Process Engineering and Advanced Technology Institute University of Surrey  Guilford Surrey GU27XH UK"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2023,2,8]]},"reference":[{"key":"e_1_2_3_1_1","unstructured":"\u00a0"},{"key":"e_1_2_3_2_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.1137014"},{"key":"e_1_2_3_3_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.309.5734.548"},{"key":"e_1_2_3_4_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201911609"},{"key":"e_1_2_3_4_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201911609"},{"key":"e_1_2_3_5_1","unstructured":"\u00a0"},{"key":"e_1_2_3_6_2","doi-asserted-by":"publisher","DOI":"10.1039\/C3CS60378D"},{"key":"e_1_2_3_7_2","doi-asserted-by":"publisher","DOI":"10.1039\/B800582F"},{"key":"e_1_2_3_8_1","unstructured":"\u00a0"},{"key":"e_1_2_3_9_2","doi-asserted-by":"publisher","DOI":"10.1021\/cs401208c"},{"key":"e_1_2_3_10_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201705926"},{"key":"e_1_2_3_10_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201705926"},{"key":"e_1_2_3_11_1","unstructured":"\u00a0"},{"key":"e_1_2_3_12_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.1c09979"},{"key":"e_1_2_3_13_2","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.1c03690"},{"key":"e_1_2_3_14_1","unstructured":"\u00a0"},{"key":"e_1_2_3_15_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c09684"},{"key":"e_1_2_3_16_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202202328"},{"key":"e_1_2_3_16_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.202202328"},{"key":"e_1_2_3_17_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202200413"},{"key":"e_1_2_3_17_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.202200413"},{"key":"e_1_2_3_18_1","unstructured":"\u00a0"},{"key":"e_1_2_3_19_2","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201904433"},{"key":"e_1_2_3_20_2","doi-asserted-by":"publisher","DOI":"10.1002\/adsu.202100184"},{"key":"e_1_2_3_21_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41563-019-0398-0"},{"key":"e_1_2_3_22_1","doi-asserted-by":"publisher","DOI":"10.1038\/s42004-020-00421-x"},{"key":"e_1_2_3_23_1","unstructured":"\u00a0"},{"key":"e_1_2_3_24_2","doi-asserted-by":"publisher","DOI":"10.1007\/s12274-021-3517-6"},{"key":"e_1_2_3_25_2","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202103224"},{"key":"e_1_2_3_26_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.1c04622"},{"key":"e_1_2_3_27_1","unstructured":"\u00a0"},{"key":"e_1_2_3_28_2","doi-asserted-by":"publisher","DOI":"10.1021\/jp066654x"},{"key":"e_1_2_3_29_2","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.0c01958"},{"key":"e_1_2_3_30_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.renene.2021.04.100"},{"key":"e_1_2_3_31_1","unstructured":"\u00a0"},{"key":"e_1_2_3_32_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2022.121379"},{"key":"e_1_2_3_33_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2018.01.060"},{"key":"e_1_2_3_34_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201102011"},{"key":"e_1_2_3_34_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201102011"},{"key":"e_1_2_3_35_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5TA03628C"},{"key":"e_1_2_3_36_1","doi-asserted-by":"publisher","DOI":"10.1021\/cm071572m"},{"key":"e_1_2_3_37_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.elecom.2009.01.015"},{"key":"e_1_2_3_38_1","unstructured":"\u00a0"},{"key":"e_1_2_3_39_2","doi-asserted-by":"publisher","DOI":"10.1007\/s10967-014-3758-x"},{"key":"e_1_2_3_40_2","doi-asserted-by":"publisher","DOI":"10.1002\/pola.1993.080310725"},{"key":"e_1_2_3_41_1","doi-asserted-by":"publisher","DOI":"10.1021\/la4020288"},{"key":"e_1_2_3_42_1","doi-asserted-by":"publisher","DOI":"10.1039\/C6CC04523E"},{"key":"e_1_2_3_43_1","doi-asserted-by":"publisher","DOI":"10.1080\/05704928.2010.537004"},{"key":"e_1_2_3_44_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.8b12428"},{"key":"e_1_2_3_45_1","doi-asserted-by":"publisher","DOI":"10.1063\/1.49373"},{"key":"e_1_2_3_46_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201813967"},{"key":"e_1_2_3_46_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201813967"},{"key":"e_1_2_3_47_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b10476"},{"key":"e_1_2_3_48_1","unstructured":"\u00a0"},{"key":"e_1_2_3_49_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2022.137080"},{"key":"e_1_2_3_50_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b10662"},{"key":"e_1_2_3_51_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.1c00802"},{"key":"e_1_2_3_52_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200903886"},{"key":"e_1_2_3_52_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200903886"},{"key":"e_1_2_3_53_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.8b05050"},{"key":"e_1_2_3_54_1","doi-asserted-by":"publisher","DOI":"10.1002\/solr.202200427"},{"key":"e_1_2_3_55_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c02225"},{"key":"e_1_2_3_56_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202001922"},{"key":"e_1_2_3_57_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.6b03370"},{"key":"e_1_2_3_58_1","unstructured":"\u00a0"},{"key":"e_1_2_3_59_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201804978"},{"key":"e_1_2_3_59_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201804978"},{"key":"e_1_2_3_60_2","first-page":"1388","volume":"45","author":"Pankratov D.","year":"2000","journal-title":"Russ. J. Inorg. Chem."},{"key":"e_1_2_3_61_1","unstructured":"\u00a0"},{"key":"e_1_2_3_62_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.carbon.2014.05.019"},{"key":"e_1_2_3_63_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.cattod.2005.02.023"}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.202218318","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/anie.202218318","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.202218318","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,4,8]],"date-time":"2025-04-08T13:06:59Z","timestamp":1744117619000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.202218318"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2023,2,8]]},"references-count":71,"journal-issue":{"issue":"12","published-print":{"date-parts":[[2023,3,13]]}},"alternative-id":["10.1002\/anie.202218318"],"URL":"https:\/\/doi.org\/10.1002\/anie.202218318","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2023,2,8]]},"assertion":[{"value":"2022-12-12","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2023-02-08","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e202218318"}}