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These adducts include the parent phosphinidene, PH, which is accessed via thermolysis of coordinated HPCO. The reported FLP\u2010PH species acts as a springboard to other phosphorus\u2010containing compounds, such as FLP\u2010adducts of diphosphorus (P\n                    <jats:sub>2<\/jats:sub>\n                    ) and InP\n                    <jats:sub>3<\/jats:sub>\n                    . Our new adducts participate in thermal\u2010 or light\u2010induced phosphinidene elimination (of both PH and PR, R=organic group), transfer P\n                    <jats:sub>2<\/jats:sub>\n                    units to an organic substrate, and yield the useful semiconductor InP at only 110\u2009\u00b0C from solution.\n                  <\/jats:p>","DOI":"10.1002\/anie.202218587","type":"journal-article","created":{"date-parts":[[2023,1,10]],"date-time":"2023-01-10T09:15:21Z","timestamp":1673342121000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":29,"title":["Frustrated Lewis Pair Adduct of Atomic P(\u22121) as a Source of Phosphinidenes (PR), Diphosphorus (P\n                    <sub>2<\/sub>\n                    ), and Indium Phosphide"],"prefix":"10.1002","volume":"62","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-9527-6218","authenticated-orcid":false,"given":"Brandon L.","family":"Frenette","sequence":"first","affiliation":[{"name":"Department of Chemistry University of Alberta 11227 Saskatchewan Dr. Edmonton Alberta T6G 2G2 Canada"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9254-8502","authenticated-orcid":false,"given":"Jonathan","family":"Trach","sequence":"additional","affiliation":[{"name":"Department of Chemistry University of Alberta 11227 Saskatchewan Dr. Edmonton Alberta T6G 2G2 Canada"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5221-4401","authenticated-orcid":false,"given":"Michael J.","family":"Ferguson","sequence":"additional","affiliation":[{"name":"Department of Chemistry University of Alberta 11227 Saskatchewan Dr. Edmonton Alberta T6G 2G2 Canada"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0360-0090","authenticated-orcid":false,"given":"Eric","family":"Rivard","sequence":"additional","affiliation":[{"name":"Department of Chemistry University of Alberta 11227 Saskatchewan Dr. Edmonton Alberta T6G 2G2 Canada"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2023,1,25]]},"reference":[{"key":"e_1_2_7_1_1","unstructured":"\u00a0"},{"key":"e_1_2_7_2_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00405a054"},{"key":"e_1_2_7_3_2","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.202000878"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chempr.2016.04.001"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.201800459"},{"key":"e_1_2_7_6_1","unstructured":"\u00a0"},{"key":"e_1_2_7_7_2","doi-asserted-by":"publisher","DOI":"10.1039\/a802722f"},{"key":"e_1_2_7_8_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0010-8545(00)00311-8"},{"key":"e_1_2_7_9_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.2c03302"},{"key":"e_1_2_7_10_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202207064"},{"key":"e_1_2_7_10_3","doi-asserted-by":"crossref","first-page":"e202207064","DOI":"10.1002\/ange.202207064","volume":"134","year":"2022","journal-title":"Angew. Chem."},{"key":"e_1_2_7_11_1","unstructured":"\u00a0"},{"key":"e_1_2_7_12_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.1134230"},{"key":"e_1_2_7_13_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201409800"},{"key":"e_1_2_7_13_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201409800"},{"key":"e_1_2_7_14_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja0637494"},{"key":"e_1_2_7_15_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202012218"},{"key":"e_1_2_7_15_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.202012218"},{"key":"e_1_2_7_16_1","unstructured":"For similar FLP adducts of tetrelenes see:"},{"key":"e_1_2_7_17_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202001354"},{"key":"e_1_2_7_17_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.202001354"},{"key":"e_1_2_7_18_2","doi-asserted-by":"publisher","DOI":"10.1039\/D2DT03807B"},{"key":"e_1_2_7_19_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1CC04923B"},{"key":"e_1_2_7_20_1","unstructured":"\u00a0"},{"key":"e_1_2_7_21_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja306902j"},{"key":"e_1_2_7_22_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja507922x"},{"key":"e_1_2_7_23_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.aab0204"},{"key":"e_1_2_7_24_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.8b09845"},{"key":"e_1_2_7_25_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.8b10775"},{"key":"e_1_2_7_26_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.1c03333"},{"key":"e_1_2_7_27_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41557-022-00958-5"},{"key":"e_1_2_7_28_1","unstructured":"\u00a0"},{"key":"e_1_2_7_29_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201400798"},{"key":"e_1_2_7_29_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201400798"},{"key":"e_1_2_7_30_2","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms12884"},{"key":"e_1_2_7_31_1","unstructured":"\u00a0"},{"key":"e_1_2_7_32_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201703870"},{"key":"e_1_2_7_32_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201703870"},{"key":"e_1_2_7_33_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.6b01276"},{"key":"e_1_2_7_34_1","unstructured":"\u00a0"},{"key":"e_1_2_7_35_2","doi-asserted-by":"publisher","DOI":"10.1021\/om100335j"},{"key":"e_1_2_7_36_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja4072699"},{"key":"e_1_2_7_37_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201303906"},{"key":"e_1_2_7_38_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200801741"},{"key":"e_1_2_7_38_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200801741"},{"key":"e_1_2_7_39_1","unstructured":"\u00a0"},{"key":"e_1_2_7_40_2","doi-asserted-by":"publisher","DOI":"10.1039\/C3SC53140F"},{"key":"e_1_2_7_41_2","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.201501017"},{"key":"e_1_2_7_42_1","unstructured":"\u00a0"},{"key":"e_1_2_7_43_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201700368"},{"key":"e_1_2_7_43_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201700368"},{"key":"e_1_2_7_44_2","doi-asserted-by":"publisher","DOI":"10.1016\/0009-2614(91)80084-B"},{"key":"e_1_2_7_45_2","doi-asserted-by":"publisher","DOI":"10.1016\/S1386-1425(00)00449-2"},{"key":"e_1_2_7_46_2","doi-asserted-by":"publisher","DOI":"10.1039\/c3sc52027g"},{"key":"e_1_2_7_47_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jms.2014.12.019"},{"key":"e_1_2_7_48_2","doi-asserted-by":"publisher","DOI":"10.1039\/D1CP02860J"},{"key":"e_1_2_7_49_1","unstructured":"PB{HPCO}is reminiscent of FLP adducts of isocyanates."},{"key":"e_1_2_7_50_2","doi-asserted-by":"publisher","DOI":"10.1039\/b805161e"},{"key":"e_1_2_7_51_2","doi-asserted-by":"publisher","DOI":"10.1039\/c0dt00015a"},{"key":"e_1_2_7_52_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja210214r"},{"key":"e_1_2_7_53_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201803888"},{"key":"e_1_2_7_53_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201803888"},{"key":"e_1_2_7_54_1","unstructured":"Computations were performed at the:"},{"key":"e_1_2_7_55_2","unstructured":"M06-2X\/cc-pVTZ level;"},{"key":"e_1_2_7_56_2","unstructured":"M06-2X\/cc-pVDZ level;"},{"key":"e_1_2_7_57_2","unstructured":"PBE0-GD3\/cc-pVDZ level."},{"key":"e_1_2_7_58_1","unstructured":"For full synthetic crystallographic and computational data see the Supporting Information. Deposition numbers\u20052208954 2208955 2208956 2208957 2208958 2208959 2208960 2208961 and 2226180contain the supplementary crystallographic data for this paper. These data are provided free of charge by the joint Cambridge Crystallographic Data Centre and Fachinformationszentrum KarlsruheAccess Structures service."},{"key":"e_1_2_7_59_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0022-328X(00)00284-9"},{"key":"e_1_2_7_60_1","doi-asserted-by":"publisher","DOI":"10.1021\/ic301208d"},{"key":"e_1_2_7_61_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja501313s"},{"key":"e_1_2_7_62_1","doi-asserted-by":"publisher","DOI":"10.1002\/zaac.19895770103"},{"key":"e_1_2_7_63_1","unstructured":"The literature mentions [P(C6F5)]4a few times. In its first report by Cowley and Pinnel in 1966 it was misidentified as [P(C6F5)]5(as was later pointed out by West) then correctly reported in 1967 by Glemser. In the Supporting Information we provide a convenient synthesis of [P(C6F5)]4via Zn reduction of Cl2P(C6F5) and provide detailed NMR data. See:"},{"key":"e_1_2_7_64_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00971a060"},{"key":"e_1_2_7_65_2","doi-asserted-by":"publisher","DOI":"10.1007\/BF00608768"},{"key":"e_1_2_7_66_2","doi-asserted-by":"publisher","DOI":"10.1039\/c29700001120"},{"key":"e_1_2_7_67_2","doi-asserted-by":"publisher","DOI":"10.1039\/j19710001083"},{"key":"e_1_2_7_68_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2022.214499"},{"key":"e_1_2_7_69_1","unstructured":"\u00a0"},{"key":"e_1_2_7_70_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja807828t"},{"key":"e_1_2_7_71_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41557-020-0518-0"},{"key":"e_1_2_7_72_1","unstructured":"\u00a0"},{"key":"e_1_2_7_73_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja028446y"},{"key":"e_1_2_7_74_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.1129630"},{"key":"e_1_2_7_75_2","doi-asserted-by":"publisher","DOI":"10.1039\/C5SC04504E"},{"key":"e_1_2_7_76_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201905130"},{"key":"e_1_2_7_76_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201905130"},{"key":"e_1_2_7_77_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.chempr.2021.06.006"},{"key":"e_1_2_7_78_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.1c02482"},{"key":"e_1_2_7_79_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.abn7100"},{"key":"e_1_2_7_80_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201805932"},{"key":"e_1_2_7_81_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201004385"},{"key":"e_1_2_7_81_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201004385"},{"key":"e_1_2_7_82_1","unstructured":"For selected examples see:"},{"key":"e_1_2_7_83_2","doi-asserted-by":"publisher","DOI":"10.1016\/S1369-7021(09)70110-5"},{"key":"e_1_2_7_84_2","doi-asserted-by":"publisher","DOI":"10.1007\/s12274-021-4038-z"},{"key":"e_1_2_7_85_2","doi-asserted-by":"publisher","DOI":"10.1038\/35051047"},{"key":"e_1_2_7_86_1","doi-asserted-by":"publisher","DOI":"10.1016\/0022-1902(60)80196-0"},{"key":"e_1_2_7_87_1","unstructured":"\u00a0"},{"key":"e_1_2_7_88_2","doi-asserted-by":"publisher","DOI":"10.1039\/c39890000359"},{"key":"e_1_2_7_89_2","doi-asserted-by":"publisher","DOI":"10.1016\/0022-0248(91)90486-O"},{"key":"e_1_2_7_90_2","doi-asserted-by":"publisher","DOI":"10.1021\/cm00015a001"},{"key":"e_1_2_7_91_2","doi-asserted-by":"publisher","DOI":"10.1021\/cm00052a027"},{"key":"e_1_2_7_92_2","doi-asserted-by":"publisher","DOI":"10.1021\/j100070a004"},{"key":"e_1_2_7_93_2","doi-asserted-by":"publisher","DOI":"10.1021\/j100019a063"},{"key":"e_1_2_7_94_1","unstructured":"\u00a0"},{"key":"e_1_2_7_95_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.198912081"},{"key":"e_1_2_7_95_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.19891010908"},{"key":"e_1_2_7_96_2","doi-asserted-by":"publisher","DOI":"10.1088\/0268-1242\/3\/10\/016"},{"key":"e_1_2_7_97_2","doi-asserted-by":"publisher","DOI":"10.1016\/0022-328X(93)80126-V"},{"key":"e_1_2_7_98_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic00004a002"},{"key":"e_1_2_7_99_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0167-577X(03)00371-9"},{"key":"e_1_2_7_100_1","unstructured":"The authors report crystalline InP synthesis at bulk solution temperatures of 111\u2009\u00b0C but this is only possible when using a heating mantle due to localized hot spots. When using an oil bath temperatures \u2265157\u2009\u00b0C were required. In our thermolysis of[PB{P}]3In an oil bath set at 110\u2009\u00b0C was used. 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