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The methodology enjoys broad substrate scope on both 3,3\u2010disubstituted cyclopropenes and diarylphosphines. The high stereoselectivity is attributed to both the high stability of the Cu(I)\u2010(<jats:italic>R<\/jats:italic>,<jats:italic>R<\/jats:italic>)\u2010QUINOXP* complex in the presence of stoichiometric HPPh<jats:sub>2<\/jats:sub> and the produced phosphines, and the high\u2010performance asymmetric induction of the Cu(I)\u2010(<jats:italic>R<\/jats:italic>,<jats:italic>R<\/jats:italic>)\u2010QUINOXP* complex. Finally, the method is used for the synthesis of new chiral phosphine\u2010olefin compounds built on a cyclopropane skeleton, one of which serves as a wonderful ligand in Rh\u2010catalyzed asymmetric conjugate addition of phenylboronic acid to various \u03b1,\u03b2\u2010unsaturated compounds.<\/jats:p>","DOI":"10.1002\/anie.202218798","type":"journal-article","created":{"date-parts":[[2023,8,18]],"date-time":"2023-08-18T02:45:02Z","timestamp":1692326702000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":48,"title":["Copper(I)\u2010Catalyzed Asymmetric Hydrophosphination of 3,3\u2010Disubstituted Cyclopropenes"],"prefix":"10.1002","volume":"62","author":[{"given":"Shuai","family":"Zhang","sequence":"first","affiliation":[{"name":"CAS Key Laboratory of Synthetic Chemistry of Natural Substances Center for Excellence in Molecular Synthesis Shanghai Institute of Organic Chemistry University of Chinese Academy of Sciences Chinese 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