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However, 2D <jats:italic>c<\/jats:italic>\u2010MOFs with band gaps in the Vis\u2010NIR and high charge carrier mobility are rare. Most of the reported conducting 2D <jats:italic>c\u2010<\/jats:italic>MOFs are metallic (i.e. gapless), which largely limits their use in logic devices. Herein, we design a phenanthrotriphenylene\u2010based, D<jats:sub>2h<\/jats:sub>\u2010symmetric \u03c0\u2010extended ligand (<jats:bold>OHPTP<\/jats:bold>), and synthesize the first rhombic 2D <jats:italic>c\u2010<\/jats:italic>MOF single crystals (<jats:bold>Cu<jats:sub>2<\/jats:sub>(OHPTP)<\/jats:bold>). The continuous rotation electron diffraction (cRED) analysis unveils the orthorhombic crystal structure at the atomic level with a unique slipped AA stacking. The <jats:bold>Cu<jats:sub>2<\/jats:sub>(OHPTP)<\/jats:bold> is a <jats:italic>p<\/jats:italic>\u2010type semiconductor with an indirect band gap of \u22480.50\u2005eV and exhibits high electrical conductivity of 0.10\u2005S\u2009cm<jats:sup>\u22121<\/jats:sup> and high charge carrier mobility of \u224810.0\u2005cm<jats:sup>2<\/jats:sup>\u2005V<jats:sup>\u22121<\/jats:sup>\u2009s<jats:sup>\u22121<\/jats:sup>. Theoretical calculations underline the predominant role of the out\u2010of\u2010plane charge transport in this semiquinone\u2010based 2D <jats:italic>c\u2010<\/jats:italic>MOF.<\/jats:p>","DOI":"10.1002\/anie.202300186","type":"journal-article","created":{"date-parts":[[2023,3,2]],"date-time":"2023-03-02T16:04:30Z","timestamp":1677773070000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":45,"title":["Near IR Bandgap Semiconducting 2D Conjugated Metal\u2010Organic Framework with Rhombic Lattice and High Mobility"],"prefix":"10.1002","volume":"62","author":[{"given":"Lukas","family":"Sporrer","sequence":"first","affiliation":[{"name":"Chair of Molecular Functional Materials Faculty of Chemistry and Food Chemistry Technische Universit\u00e4t Dresden  Mommsenstrasse 4 01062 Dresden 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