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We report a reaction pathway dictated by the Ru coordination environment by examining the binding geometries of adsorbates on differently coordinated Ru centers and their evolution during PET hydrogenolysis. A BTX yield of 77\u2009% was obtained using a Ru\/TiO<jats:sub>2<\/jats:sub> with a Ru coordination number of ca. 5.0 where edge\/corner sites are dominant, while more gas and saturated products were formed for Ru\/TiO<jats:sub>2<\/jats:sub> containing primarily terrace sites. Density functional theory and isotopic labelling revealed that under\u2010coordinated Ru edge sites favor \u201cupright\u201d adsorption of aromatic adsorbates while well\u2010coordinated Ru sites favor \u201cflat\u2010lying\u201d adsorption, where the former mitigates ring hydrogenation and opening. 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