{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,23]],"date-time":"2026-09-23T12:48:16Z","timestamp":1790167696783,"version":"4.1.0"},"reference-count":73,"publisher":"Wiley","issue":"19","license":[{"start":{"date-parts":[[2023,3,29]],"date-time":"2023-03-29T00:00:00Z","timestamp":1680048000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100012166","name":"National Key Research and Development Program of China","doi-asserted-by":"publisher","award":["2019YFA0705104"],"award-info":[{"award-number":["2019YFA0705104"]}],"id":[{"id":"10.13039\/501100012166","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2023,5,2]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Though massive efforts have been devoted to exploring Br\u2010based batteries, the highly soluble Br\n                    <jats:sub>2<\/jats:sub>\n                    \/Br\n                    <jats:sub>3<\/jats:sub>\n                    <jats:sup>\u2212<\/jats:sup>\n                    species causing rigorous \u201cshuttle effect\u201d, leads to severe self\u2010discharge and low Coulombic efficiency. Conventionally, quaternary ammonium salts such as methyl ethyl morpholinium bromide (MEMBr) and tetrapropylammonium bromide (TPABr) are used to fix Br\n                    <jats:sub>2<\/jats:sub>\n                    and Br\n                    <jats:sub>3<\/jats:sub>\n                    <jats:sup>\u2212<\/jats:sup>\n                    , but they occupy the mass and volume of battery without capacity contribution. Here, we report an all\u2010active solid interhalogen compound, IBr, as a cathode to address the above challenges, in which the oxidized Br\n                    <jats:sup>0<\/jats:sup>\n                    is fixed by iodine (I), thoroughly eliminating cross\u2010diffusing Br\n                    <jats:sub>2<\/jats:sub>\n                    \/Br\n                    <jats:sub>3<\/jats:sub>\n                    <jats:sup>\u2212<\/jats:sup>\n                    species during the whole charging and discharging process. The Zn||IBr battery delivers remarkably high energy density of 385.8\u2005Wh\u2009kg\n                    <jats:sup>\u22121<\/jats:sup>\n                    , which is higher than those of I\n                    <jats:sub>2<\/jats:sub>\n                    , MEMBr\n                    <jats:sub>3<\/jats:sub>\n                    , and TPABr\n                    <jats:sub>3<\/jats:sub>\n                    cathodes. Our work provides new approaches to achieve active solid interhalogen chemistry for high\u2010energy electrochemical energy storage devices.\n                  <\/jats:p>","DOI":"10.1002\/anie.202301467","type":"journal-article","created":{"date-parts":[[2023,3,7]],"date-time":"2023-03-07T22:20:15Z","timestamp":1678227615000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":55,"title":["Solid Interhalogen Compounds with Effective Br\n                    <sup>0<\/sup>\n                    Fixing for Stable High\u2010energy Zinc Batteries"],"prefix":"10.1002","volume":"62","author":[{"given":"Shengmei","family":"Chen","sequence":"first","affiliation":[{"name":"Department of Materials Science and Engineering City University of Hong Kong  83 Tat Chee Avenue, Kowloon Hong Kong 999077 P. R. 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