{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,22]],"date-time":"2026-10-22T08:46:56Z","timestamp":1792658816607,"version":"4.5.0"},"reference-count":46,"publisher":"Wiley","issue":"29","license":[{"start":{"date-parts":[[2023,6,12]],"date-time":"2023-06-12T00:00:00Z","timestamp":1686528000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["21975145"],"award-info":[{"award-number":["21975145"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2023,7,17]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Supramolecular interactions facilitate the development of tough multifunctional thermoplastic elastomers. However, the fundamental principles that govern supramolecular toughening are barely understood, and the rational design to achieve the desired high toughness remains daunting. Herein, we report a simple and robust method for toughening thermoplastic elastomers by rationally tailoring hard\u2013soft phase separation structures containing rigid and flexible supramolecular segments. The introduced functional segments with distinct structural rigidities provide mismatched supramolecular interactions to efficiently tune the energy dissipation and bear an external load. The optimal supramolecular elastomer containing aromatic amide and acylsemicarbazide moieties demonstrates a record toughness (1.2\u2005GJ\u2009m\n                    <jats:sup>\u22123<\/jats:sup>\n                    ), extraordinary crack tolerance (fracture energy 282.5\u2005kJ\u2009m\n                    <jats:sup>\u22122<\/jats:sup>\n                    ), an ultrahigh true stress at break (2.3\u2005GPa), good elasticity, healing ability, recyclability, and impact resistance. The toughening mechanism is validated by testing various elastomers, confirming the potential for designing and developing super\u2010tough supramolecular materials with promising applications in aerospace and electronics.\n                  <\/jats:p>","DOI":"10.1002\/anie.202301762","type":"journal-article","created":{"date-parts":[[2023,5,20]],"date-time":"2023-05-20T00:13:13Z","timestamp":1684541593000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":197,"title":["Development of Tough Thermoplastic Elastomers by Leveraging Rigid\u2013Flexible Supramolecular Segment Interplays"],"prefix":"10.1002","volume":"62","author":[{"given":"Luping","family":"Wang","sequence":"first","affiliation":[{"name":"National Engineering Research Center for Colloidal Materials, School of Chemistry and Chemical Engineering Shandong University  Jinan, Shandong 250100 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Longfei","family":"Guo","sequence":"additional","affiliation":[{"name":"National Engineering Research Center for Colloidal Materials, School of Chemistry and Chemical Engineering Shandong University  Jinan, Shandong 250100 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kaiqiang","family":"Zhang","sequence":"additional","affiliation":[{"name":"National Engineering Research Center for Colloidal Materials, School of Chemistry and Chemical Engineering Shandong University  Jinan, Shandong 250100 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0405-3439","authenticated-orcid":false,"given":"Yuguo","family":"Xia","sequence":"additional","affiliation":[{"name":"National Engineering Research Center for Colloidal Materials, School of Chemistry and Chemical Engineering Shandong University  Jinan, Shandong 250100 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9760-9677","authenticated-orcid":false,"given":"Jingcheng","family":"Hao","sequence":"additional","affiliation":[{"name":"Key Laboratory of Colloid and Interface Chemistry of the Ministry of Education Shandong University  Jinan, Shandong 250100 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6646-0515","authenticated-orcid":false,"given":"Xu","family":"Wang","sequence":"additional","affiliation":[{"name":"National Engineering Research Center for Colloidal Materials, School of Chemistry and Chemical Engineering Shandong University  Jinan, Shandong 250100 P. R. China"},{"name":"Key Laboratory of Colloid and Interface Chemistry of the Ministry of Education Shandong University  Jinan, Shandong 250100 P. R. 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