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Herein, a robust metal\u2013organic framework (MOF) {[Th<jats:sub>6<\/jats:sub>O<jats:sub>4<\/jats:sub>(OH)<jats:sub>4<\/jats:sub>(H<jats:sub>2<\/jats:sub>O)<jats:sub>6<\/jats:sub>(BCP)<jats:sub>3<\/jats:sub>]\u22c510\u2009DMF}<jats:sub><jats:italic>n<\/jats:italic><\/jats:sub> (<jats:bold>1<\/jats:bold>) containing stacked nanocages with a diameter of 1.55\u2005nm was constructed. Compound <jats:bold>1<\/jats:bold> can maintain its single\u2010crystal structure even kept in air at 400\u2009\u00b0C for 3\u2005h, and in DMF or water at 200\u2009\u00b0C for 7\u2005days. Density functional theory (DFT) calculations suggested that the high interaction energy between the [Th<jats:sub>6<\/jats:sub>O<jats:sub>4<\/jats:sub>(OH)<jats:sub>4<\/jats:sub>(H<jats:sub>2<\/jats:sub>O)<jats:sub>6<\/jats:sub>]<jats:sup>12+<\/jats:sup> clusters and ligands was responsible for the excellent stability of <jats:bold>1<\/jats:bold>. Catalytic investigations revealed that <jats:bold>1<\/jats:bold> can effectively and size\u2010selectively catalyze the reductive amination of aldehydes with DMF, and it can be reused at least five times without obvious loss in catalytic activity.<\/jats:p>","DOI":"10.1002\/anie.202301764","type":"journal-article","created":{"date-parts":[[2023,4,4]],"date-time":"2023-04-04T03:05:45Z","timestamp":1680577545000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":25,"title":["A Strong\u2010Acid\u2010Resistant [Th<sub>6<\/sub>] Cluster\u2010Based Framework for Effectively and Size\u2010Selectively Catalyzing Reductive Amination of Aldehydes with <i>N<\/i>,<i>N<\/i>\u2010Dimethylformamide"],"prefix":"10.1002","volume":"62","author":[{"given":"Xue\u2010Rui","family":"Tian","sequence":"first","affiliation":[{"name":"Renewable Energy Conversion and Storage Center, Key Laboratory of Advanced Energy Material Chemistry Department of Chemistry, Nankai University  Tianjin 300071 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhi\u2010Yu","family":"Jiang","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Engineering Research Center of Advanced Rare-Earth Materials of Ministry of Education Tsinghua University  Beijing 100084 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sheng\u2010Li","family":"Hou","sequence":"additional","affiliation":[{"name":"Renewable Energy Conversion and Storage Center, Key Laboratory of Advanced Energy Material Chemistry Department of Chemistry, Nankai University  Tianjin 300071 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Han\u2010Shi","family":"Hu","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Engineering Research Center of Advanced Rare-Earth Materials of Ministry of Education Tsinghua University  Beijing 100084 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