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Key to developing better displays is the advancement of strategies for rationally designing emissive materials that are tunable and efficient. We report a series of emissive metal\u2010organic frameworks (MOFs) generated using BUT\u201010 (BUT: Beijing University of Technology) that emits green light with <jats:italic>\u03bb<\/jats:italic><jats:sub>max<\/jats:sub> at 525\u2005nm. Post\u2010synthetic reduction of the ketone on the fluorenone ligand in BUT\u201010 generates new materials, BUT\u201010\u2010M and BUT\u201010\u2010R. The emission for BUT\u201010\u2010R is hypsochromically\u2010shifted by 113\u2005nm. Multivariate BUT\u201010\u2010M structures demonstrate emission with two maxima corresponding to the emission of both fluorenol and fluorenone moieties present in their structures. Our study represents a novel post\u2010synthetic ligand reduction strategy for producing emissive MOFs with tunable emission ranging from green, white\u2010blue to deep blue.<\/jats:p>","DOI":"10.1002\/anie.202302123","type":"journal-article","created":{"date-parts":[[2023,3,16]],"date-time":"2023-03-16T17:34:29Z","timestamp":1678988069000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":16,"title":["Hypsochromically\u2010shifted Emission of Metal\u2010organic Frameworks Generated through Post\u2010synthetic Ligand Reduction"],"prefix":"10.1002","volume":"62","author":[{"given":"Kyle T.","family":"Smith","sequence":"first","affiliation":[{"name":"Materials Discovery Laboratory (MaD Lab) Oregon State University  Corvallis OR 97331 USA"},{"name":"Department of Chemistry Oregon State University  Corvallis OR97331 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