{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,25]],"date-time":"2026-09-25T02:31:48Z","timestamp":1790303508131,"version":"4.1.0"},"reference-count":54,"publisher":"Wiley","issue":"20","license":[{"start":{"date-parts":[[2023,4,7]],"date-time":"2023-04-07T00:00:00Z","timestamp":1680825600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["21531006"],"award-info":[{"award-number":["21531006"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22271203"],"award-info":[{"award-number":["22271203"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100012462","name":"Collaborative Innovation Center of Suzhou Nano Science and Technology","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100012462","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100011195","name":"Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences","doi-asserted-by":"publisher","award":["KF2021005"],"award-info":[{"award-number":["KF2021005"]}],"id":[{"id":"10.13039\/501100011195","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2023,5,8]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    We report a unique vinyl coordination polymer (CP), [Zn(4\u2010Fb)\n                    <jats:sub>2<\/jats:sub>\n                    (tkpvb)]\n                    <jats:sub>\n                      <jats:italic>n<\/jats:italic>\n                    <\/jats:sub>\n                    (\n                    <jats:bold>1<\/jats:bold>\n                    , 4\u2010HFb=4\u2010fluorobenzoic acid, tkpvb=1,2,4,5\u2010tetrakis(4\u2010pyridylvinyl)benzene) that undergoes a rare photopolymerization reaction to form a two\u2010dimensional CP integrated with a one\u2010dimensional linear organic polymer. Upon light irradiation at different wavelengths,\n                    <jats:bold>1<\/jats:bold>\n                    exhibits an unprecedented phenomenon of photoinduced nonlinear lattice expansion.\n                    <jats:bold>1<\/jats:bold>\n                    can be uniformly dispersed in polyvinyl alcohol (PVA) to form the composite film of\n                    <jats:bold>1\u2010PVA<\/jats:bold>\n                    . When this film is exposed to UV light, internal minute stresses within crystallites are released by lattice expansion, resulting in a variety of photopolymerization\u2010driven macroscopic mechanical motions. The findings provide new insights into the conversion of small lattice expansions of CPs into macroscopic mechanical motions based on photopolymerization reactions, which can promote the development of CPs\u2010based smart photoactuators in the burgeoning field of microrobotics.\n                  <\/jats:p>","DOI":"10.1002\/anie.202302429","type":"journal-article","created":{"date-parts":[[2023,3,15]],"date-time":"2023-03-15T12:34:59Z","timestamp":1678883699000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":50,"title":["Photopolymerization\u2010Driven Macroscopic Mechanical Motions of a Composite Film Containing a Vinyl Coordination Polymer"],"prefix":"10.1002","volume":"62","author":[{"given":"Zhan\u2010Yong","family":"Yang","sequence":"first","affiliation":[{"name":"College of Chemistry Chemical Engineering and Materials Science Soochow University  Suzhou 215123 Jiangsu P. R. China"},{"name":"State Key Laboratory of Organometallic Chemistry Shanghai Institute of Organic Chemistry Chinese Academy of Sciences  Shanghai 200032 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiao","family":"Sang","sequence":"additional","affiliation":[{"name":"College of Chemistry Chemical Engineering and Materials Science Soochow University  Suzhou 215123 Jiangsu P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Dong","family":"Liu","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering Huaiyin Normal University  Huaian 223300 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qiu\u2010Yi","family":"Li","sequence":"additional","affiliation":[{"name":"College of Chemistry Chemical Engineering and Materials Science Soochow University  Suzhou 215123 Jiangsu P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Feifan","family":"Lang","sequence":"additional","affiliation":[{"name":"College of Chemistry and Molecular Engineering Zhengzhou University  Zhengzhou 450001 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2957-860X","authenticated-orcid":false,"given":"Brendan F.","family":"Abrahams","sequence":"additional","affiliation":[{"name":"School of Chemistry University of Melbourne  Victoria 3010 Australia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hongwei","family":"Hou","sequence":"additional","affiliation":[{"name":"College of Chemistry and Molecular Engineering Zhengzhou University  Zhengzhou 450001 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4377-604X","authenticated-orcid":false,"given":"Pierre","family":"Braunstein","sequence":"additional","affiliation":[{"name":"Universit\u00e9 de Strasbourg \u2013 CNRS Institut de Chimie (UMR 7177 CNRS)  4 rue Blaise Pascal-CS 90032 67081 Strasbourg France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2942-7385","authenticated-orcid":false,"given":"Jian\u2010Ping","family":"Lang","sequence":"additional","affiliation":[{"name":"College of Chemistry Chemical Engineering and Materials Science Soochow University  Suzhou 215123 Jiangsu P. R. China"},{"name":"State Key Laboratory of Organometallic Chemistry Shanghai Institute of Organic Chemistry Chinese Academy of Sciences  Shanghai 200032 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2023,4,7]]},"reference":[{"key":"e_1_2_7_1_1","doi-asserted-by":"publisher","DOI":"10.1038\/nenergy.2016.101"},{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1038\/374240a0"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201709921"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200803036"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms5293"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.1230262"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-017-02549-2"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1038\/nphoton.2015.105"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202005137"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201907574"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201705325"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c09577"},{"key":"e_1_2_7_13_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.mattod.2021.04.014"},{"key":"e_1_2_7_14_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201913383"},{"key":"e_1_2_7_15_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja412216z"},{"key":"e_1_2_7_16_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201402040"},{"key":"e_1_2_7_17_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja404192g"},{"key":"e_1_2_7_18_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.0c10797"},{"key":"e_1_2_7_19_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201901592"},{"key":"e_1_2_7_20_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201704407"},{"key":"e_1_2_7_21_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201903536"},{"key":"e_1_2_7_22_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.progpolymsci.2019.101164"},{"key":"e_1_2_7_23_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c05440"},{"key":"e_1_2_7_24_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.5b00398"},{"key":"e_1_2_7_25_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2022.214890"},{"key":"e_1_2_7_26_1","doi-asserted-by":"publisher","DOI":"10.1038\/nature19344"},{"key":"e_1_2_7_27_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.2c09285"},{"key":"e_1_2_7_28_1","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.2625"},{"key":"e_1_2_7_29_1","doi-asserted-by":"publisher","DOI":"10.1073\/pnas.2020604118"},{"key":"e_1_2_7_30_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja4063019"},{"key":"e_1_2_7_31_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201511444"},{"key":"e_1_2_7_32_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201805543"},{"key":"e_1_2_7_33_1","doi-asserted-by":"publisher","DOI":"10.1038\/nature05669"},{"key":"e_1_2_7_34_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201304670"},{"key":"e_1_2_7_35_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201706684"},{"key":"e_1_2_7_36_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b13605"},{"key":"e_1_2_7_37_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.9b00288"},{"key":"e_1_2_7_38_1","doi-asserted-by":"publisher","DOI":"10.1038\/nature07970"},{"key":"e_1_2_7_39_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.7b00490"},{"key":"e_1_2_7_40_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.8b01775"},{"key":"e_1_2_7_41_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201900221"},{"key":"e_1_2_7_42_1","doi-asserted-by":"publisher","DOI":"10.1021\/ar500335a"},{"key":"e_1_2_7_43_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201310536"},{"key":"e_1_2_7_44_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2016.06.009"},{"key":"e_1_2_7_45_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.0c00321"},{"key":"e_1_2_7_46_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9TC06689F"},{"key":"e_1_2_7_47_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201903757"},{"key":"e_1_2_7_48_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201001551"},{"key":"e_1_2_7_49_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jssc.2004.08.036"},{"key":"e_1_2_7_50_1","unstructured":"Deposition Numbers2109674 (1) 2109776 (2a) 2110775 (2b) 2110774 (2c) 2110772 (2d) 2110773 (2e) 2110777 (2f) and 2110778 (2g)contain the supplementary crystallographic data for this paper. These data are provided free of charge by the joint Cambridge Crystallographic Data Centre and Fachinformationszentrum KarlsruheAccess Structures service."},{"key":"e_1_2_7_51_1","doi-asserted-by":"publisher","DOI":"10.1351\/pac197127040647"},{"key":"e_1_2_7_52_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202014208"},{"key":"e_1_2_7_53_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201502179"},{"key":"e_1_2_7_54_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.aap8671"}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.202302429","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.202302429","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,8,19]],"date-time":"2023-08-19T14:51:57Z","timestamp":1692456717000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.202302429"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2023,4,7]]},"references-count":54,"journal-issue":{"issue":"20","published-print":{"date-parts":[[2023,5,8]]}},"alternative-id":["10.1002\/anie.202302429"],"URL":"https:\/\/doi.org\/10.1002\/anie.202302429","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2023,4,7]]},"assertion":[{"value":"2023-02-16","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2023-04-07","order":2,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e202302429"}}