{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,1]],"date-time":"2026-10-01T12:45:48Z","timestamp":1790858748358,"version":"4.1.0"},"reference-count":47,"publisher":"Wiley","issue":"24","license":[{"start":{"date-parts":[[2023,5,5]],"date-time":"2023-05-05T00:00:00Z","timestamp":1683244800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2023,5,5]],"date-time":"2023-05-05T00:00:00Z","timestamp":1683244800000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22101210, 22101211, 22090061, and 21821003"],"award-info":[{"award-number":["22101210, 22101211, 22090061, and 21821003"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2023,6,12]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Indoor detection of volatile organic compounds (VOCs) concentration is necessary due to the serious toxicity hazards even at trace level. However, physisorbents usually exhibit weak interactions especially in the presence of trace concentrations of VOCs, thus exhibiting poor responsive signal. Herein, we report a new flexible metal\u2013organic framework (MOF) that exhibits interesting pore\u2010opening behavior after immersing in H\n                    <jats:sub>2<\/jats:sub>\n                    O. The pore\u2010opening phase shows significant (\u2248116 folds) and extremely fast (&lt;1\u2005minute) fluorescence enhancement after being exposed to saturated benzene vapor. The limit of detection concentration for benzene vapor can be calculated as 0.133\u2005mg\u2009L\n                    <jats:sup>\u22121<\/jats:sup>\n                    . Thus this material represents the first MOF to achieve visual detection of trace benzene vapor by the naked eyes. Theoretical calculations and single\u2010crystal structure reveal that the special \u201cbilateral \u03c0\u2013\u03c0 stacking\u201d interactions between the host and guest, which facilitate electron transfer and greatly enhance the intensity of fluorescence.\n                  <\/jats:p>","DOI":"10.1002\/anie.202303500","type":"journal-article","created":{"date-parts":[[2023,4,17]],"date-time":"2023-04-17T23:10:12Z","timestamp":1681773012000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":78,"title":["Fluorescence Enhancement of a Metal\u2010Organic Framework for Ultra\u2010Efficient Detection of Trace Benzene Vapor"],"prefix":"10.1002","volume":"62","author":[{"given":"Wen\u2010Bin","family":"Li","sequence":"first","affiliation":[{"name":"School of Biotechnology and Health Sciences Wuyi University  Guangdong 529020 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These data are provided free of charge by the joint Cambridge Crystallographic Data Centre and Fachinformationszentrum KarlsruheAccess Structures service."},{"key":"e_1_2_7_40_1","unstructured":"\u00a0"},{"key":"e_1_2_7_41_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201601812"},{"key":"e_1_2_7_42_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5b04178"},{"key":"e_1_2_7_43_1","doi-asserted-by":"publisher","DOI":"10.1002\/asia.201901168"},{"key":"e_1_2_7_44_1","unstructured":"\u00a0"},{"key":"e_1_2_7_45_2","doi-asserted-by":"publisher","DOI":"10.1039\/C9TA06632B"},{"key":"e_1_2_7_46_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja106851d"},{"key":"e_1_2_7_47_1","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms1170"}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.202303500","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/anie.202303500","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.202303500","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,6,19]],"date-time":"2026-06-19T15:56:12Z","timestamp":1781884572000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.202303500"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2023,5,5]]},"references-count":47,"journal-issue":{"issue":"24","published-print":{"date-parts":[[2023,6,12]]}},"alternative-id":["10.1002\/anie.202303500"],"URL":"https:\/\/doi.org\/10.1002\/anie.202303500","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2023,5,5]]},"assertion":[{"value":"2023-03-10","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2023-05-05","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e202303500"}}